Synergistic assisted hydrogen production of tailings slurry and coal slurry: Process and mechanism investigation

被引:6
|
作者
Pan, Keheng [1 ,2 ]
Deng, Jijia [1 ,2 ]
Qu, Guangfei [1 ,2 ,3 ]
Wei, Kunling [1 ,2 ]
Liang, Yuqi [1 ,2 ]
机构
[1] Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650500, Yunnan, Peoples R China
[2] Natl Reg Engn Res Ctr NCW, Kunming 650500, Yunnan, Peoples R China
[3] 727 Jingming S Rd, Kunming 650500, Yunnan, Peoples R China
基金
中国国家自然科学基金;
关键词
Coal-assisted water electrolysis; Hydrogen production; Lead-zinc tailings; Ferrous ions; ELECTROLYSIS; CARBON;
D O I
10.1016/j.jclepro.2023.138582
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study investigated the process and mechanism of synergistically assisted hydrogen production from tailings and coal slurry. We have identified the optimal tailings as lead-zinc tailings through experimentation with different tailings mixed with pulverized coal. Furthermore, we have analyzed the electrochemical properties of Fe2+ and Fe3+ at different concentration gradients in a hydrochloric acid environment and our results have confirmed that the presence of Fe3+ in the simplified environment does not affect the electrochemical processes. to determine the respective roles and effects of the extract and residue of the lead-zinc tailings slurry with equal amounts of coal dust added to them, which has confirmed that it is the lead-zinc tailings extract that has the primary influence. In addition, the electrocatalysis of Fe3+ in the presence of both lead-zinc tailings and coal results in a small increase in current density, and the improvement in current density due to direct and indirect oxidation of coal particles is also extremely limited. Based on our analysis, we have concluded that the increase in current density brought about by the synergistic hydrogen production from lead-zinc tailings-supported coal is mainly due to the different oxidation processes of Fe2+.
引用
收藏
页数:9
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