Effect of waste water on hydrogen production from coal slurry electrolysis

被引:3
|
作者
Bai Q.-C. [1 ]
Liu J.-Z. [1 ]
Song Z.-Y. [1 ]
Cheng J. [1 ]
机构
[1] State Key Laboratory of Energy Clean Utilization, Zhejiang University, Hangzhou
关键词
Coal slurry; Current density; Electrolysis; Hydrogen production; Waste water;
D O I
10.3785/j.issn.1008-973X.2019.01.020
中图分类号
学科分类号
摘要
Three kinds of industrial waste water named Xiqi, Liuhuang and Tanhua were added to the anodic electrolyte of coal slurry electrolysis system in order to analyze the effect of industrial waste water on hydrogen production from coal slurry electrolysis. The current density-voltage curves before and after the addition of waste water were analyzed. Then the effect of waste water addition on current efficiency and hydrogen production rate, and the effect of waste water volume fraction and stirring speed on the electrolytic current density were analyzed. Results show that the three kinds of waste water do not change the initial electrolytic potential of coal slurry electrolysis, but have great influence on the electrolysis rate. Xiqi and Liuhuang waste water can effectively increase the current density and the rate of electrolysis. The addition of the Xiqi waste water has no effect on the hydrogen current efficiency of coal slurry electrolysis, but the current density shows a rapid increase and then a slight decrease with the increase of the volume fraction of the Xiqi waste water. The rate of waste water coal slurry electrolysis is affected by the stirring rate. The mass transfer and the current density both increase with the increase of stirring rate. © 2019, Zhejiang University Press. All right reserved.
引用
收藏
页码:180 / 185
页数:5
相关论文
共 21 条
  • [1] Liu H., Wang Z.-Z., The possibility of coal electrochemical gasification, Coal Conversion, 23, 4, pp. 11-14, (2000)
  • [2] Fang X., The mechanism and kinetics researeh for electrochemical coal gasification, (2016)
  • [3] Gong X.Z., Wang M.Y., Liu Y., Et al., Variation with time of cell voltage for coal slurry electrolysis in sulfuric acid, Energy, 65, 1, pp. 233-239, (2014)
  • [4] Coughlin R.W., Farooque M., Electrochemical gasification of coal: simultaneous production of hydrogen and carbon dioxide by a single reaction involving coal, water, and electrons, Industrial and Engineering Chemistry Process Design and Development, 19, 2, pp. 211-219, (1980)
  • [5] Sathe N., Botte G.G., Assessment of coal and graphite electrolysis on carbon fiber electrodes, Journal of Power Sources, 161, 1, pp. 513-523, (2006)
  • [6] Gong X.Z., Wang M.Y., Wang Z., Et al., Desulfuration of electrolyzed coal water slurry in HCl system with ionic liquid addition, Fuel Processing Technology, 94, 1, pp. 6-12, (2012)
  • [7] Coughlin R.W., Farooque M., Hydrogen production from coal water and electrons, Nature, 279, 5711, pp. 301-303, (1979)
  • [8] Dhooge P.M., Stilwell D.E., Park S.M., Electrochemical studies of coal slurry oxidation mechanisms, Journal of the Electrochemical Society, 129, 8, pp. 1719-1724, (1982)
  • [9] Hong L.-M., Study on anode catalyst for hydrogen production by electrolytic slurry and its reaction mechanism, (2008)
  • [10] Yin R.-H., Zhang L., Ji X.-B., Et al., Study of producing hydrogen by electrolysis of coal slurries, Modern Chemical Industry, 27, 6, pp. 27-30, (2007)