Facile synthesis of strontium selenide supported copper sulfide hybrid nanosheets as an efficient electrode for high-performance OER

被引:28
|
作者
Junaid, Ali [1 ]
Abdullah, Muhammad [2 ]
Bano, Nigarish [1 ]
Noreen, Faiqa [1 ]
Shah, Syed Imran Abbas [1 ]
Alshgari, Razan A. [1 ]
Mohammad, Saikh [3 ]
Manzoor, Sumaira [1 ]
Ehsan, Muhammad Fahad [4 ]
Ashiq, Muhammad Naeem [1 ]
机构
[1] Bahauddin Zakariya Univ, Inst Chem Sci, Multan 60800, Pakistan
[2] Govt Coll Univ, Dept Chem, Lahore, Pakistan
[3] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[4] Northeastern Univ, Dept Civil & Environm Engn, Boston, MA 02115 USA
关键词
Metal chalcogens; Metallic sulfide and selenides; Electrochemical water splitting; Oxygen evolution reaction (OER); OXYGEN EVOLUTION REACTION; ELECTROCATALYSTS;
D O I
10.1007/s43207-024-00372-2
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
To drive clean and sustainable fuel production via water electrolysis, development of high-performing, cost-effective electrocatalysts rich in earth elements without relying on precious metals or costly materials is crucial. In this study, strontium selenide (SrSe), copper sulfide (CuS), and composite SrSe@CuS via a traditional coprecipitate method under alkaline conditions are synthesized. Characterization techniques including X-ray diffraction, Transmission electron microscopy, Field emission scanning electron microscopy, and Brunauer-Emmett-Teller surface area analysis are employed to analyze the structure, morphology, and surface characteristics. The larger surface area of 123 m2 g-1 and lower crystalline size (46.43 nm) of SrSe@CuS nanosheets show more active sites for oxygen evolution reaction. The oxygen evolution activity displayed overpotentials of 290 mV, a lower tafel slope of 67 mV dec-1, and Lower charge transfer resistance (RCT) values of SrSe@CuS nanosheets (1.82 omega) surpassing the individual SrSe and CuS nanosheets. Notably, the SrSe@CuS nanosheets exhibited remarkable stability, maintaining an oxygen evolution reaction (OER) activity of 10 mA cm-2 for over 50 h and sustaining a negligible loss in performance even after 50,000 cycles of repetitive cyclivoltammetry scans. These findings highlight their potential applicability in energy conversion and storage systems.
引用
收藏
页码:469 / 481
页数:13
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