Nickel-Catalyzed Aminocarbonylation of Aryl Iodides with 1 atm CO

被引：0

作者：

Liu, Ning ^{[1
,2
]}

Wu, Xianqing ^{[1
,2
]}

Qu, Jingping ^{[1
,2
]}

Chen, Yifeng ^{[1
,2
]}

机构：

[1] East China Univ Science& Technol, Sch Chem & Mol Engn, Frontiers Sci Ctr Materiobiol & Dynam Chem, Feringa Nobel Prize Sci Joint Res Ctr,Key Lab Adv, 130 Meilong Rd, Shanghai 200237, Peoples R China

[2] East China Univ Science& Technol, Sch Chem & Mol Engn, Frontiers Sci Ctr Materiobiol & Dynam Chem, Feringa Nobel Prize Sci Joint Res Ctr,Joint Int Re, 130 Meilong Rd, Shanghai 200237, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2023年 / 18卷 / 01期

基金：

上海市自然科学基金; 中国博士后科学基金;

关键词：

nickel catalysis; amide; aminocarbonylation; carbon monoxide; cross coupling; ATMOSPHERIC-PRESSURE; REDUCTIVE AMINOCARBONYLATION; CARBONYLATIVE SYNTHESIS; COUPLING REACTIONS; N-ARYLATION; HALIDES; AMIDES; BROMIDES; AMINES; NUCLEOPHILES;

D O I：

10.1002/asia.202201061

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reported here is a nickel-catalyzed aminocarbonylation of aromatic iodides with (hetero)aryl anilines and alkyl amines under atmospheric CO pressure. The reaction features with broad substrate scope with excellent functional group tolerance, providing an expedient method for the construction of amide analogues. Notably, amino alcohols can be selectively transformed into the corresponding amides successfully without interfering the hydroxyl group under the current standard conditions.

引用

页数：5

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