Study on the passive behavior of 304 stainless steel under temperature variation

被引：3
|
作者：
Liu, Xuehui [1 ]
Sui, Yongqiang [1 ]
Zhang, Huixia [1 ]
Liu, Yapeng [1 ]
Li, Xiangbo [1 ]
Hou, Jian [1 ]
机构：
[1] Luoyang Ship Mat Inst, State Key Lab Marine Corros & Protect, 37 Wenhai Middle Rd, Qingdao 266237, Shandong, Peoples R China
来源：
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION | 2024年 / 75卷 / 07期
基金：
中国国家自然科学基金;
关键词：
304 stainless steel; passive film; pitting corrosion; X-ray photoelectron spectroscopy; STAINLESS-STEEL; CORROSION;
D O I：
10.1002/maco.202414280
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this paper, the passive behavior of 304 stainless steel (SS) in NaCl solution is studied by electrochemical methods and surface analysis. The polarization measurement results show that the pitting potential (Ep) has a simple linear relationship with the temperature increase. Scanning Kelvin probe results show that the surface potential difference on the surface of 304 SS is well correlated with the temperature. Scanning electron microscope results show that the rupture of the passive film accelerates with the increase of temperature. The X-ray photoelectron spectroscopy analysis shows that the high temperature causes more oxidation on the surface of 304 SS, leading more Cr3+ oxidized to Cr6+ at high temperature.
引用
收藏
页码：867 / 874
页数：8
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