A single carbon atom controls the geometry and reactivity of CoII(N2S2) complexes

被引：1

作者：

Jana, Manish ^{[1
]}

Quiroz, Manuel ^{[1
]}

Darensbourg, Marcetta Y. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 09期

基金：

美国国家科学基金会;

关键词：

LIGANDS; ION;

D O I：

10.1039/d3cc05394f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three- vs. two-carbon N-to-N connectors give rise to monomeric, tetrahedral N2S2Co(ii) (mu(eff) = 4.24 BM) or dimeric [(N2S2)Co(ii)](2) (diamagnetic) complexes, respectively. Differences in the derivative products of the Lewis acid receivers, W-0(CO)(3) and W-0(CO)(4), illustrate nucleophilicity of the thiolate sulfur lone pairs in each case, as well as their structural control.

引用

页码：1128 / 1131

页数：4

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