A single carbon atom controls the geometry and reactivity of CoII(N2S2) complexes

被引：1
|
作者：
Jana, Manish [1 ]
Quiroz, Manuel [1 ]
Darensbourg, Marcetta Y. [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 09期
基金：
美国国家科学基金会;
关键词：
LIGANDS; ION;
D O I：
10.1039/d3cc05394f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three- vs. two-carbon N-to-N connectors give rise to monomeric, tetrahedral N2S2Co(ii) (mu(eff) = 4.24 BM) or dimeric [(N2S2)Co(ii)](2) (diamagnetic) complexes, respectively. Differences in the derivative products of the Lewis acid receivers, W-0(CO)(3) and W-0(CO)(4), illustrate nucleophilicity of the thiolate sulfur lone pairs in each case, as well as their structural control.
引用
收藏
页码：1128 / 1131
页数：4
相关论文
共 50 条
  • [1] Tetradentate N2S2 Vanadyl(IV) Coordination Complexes: Synthesis, Characterization, and Reactivity Studies
    Jenkins, Roxanne M.
    Pinder, Tiffany A.
    Hatley, Michelle L.
    Reibenspies, Joseph H.
    Darensbourg, Marcetta Y.
    INORGANIC CHEMISTRY, 2011, 50 (05) : 1849 - 1855
  • [2] Synthesis, crystal structure and reactivity of copper(II) complexes of tetradentate N2S2 donor ligands
    Sarkar, Sandipan
    Paul, Hena
    Drew, Michael G. B.
    Zangrando, Ennio
    Chattopadhyay, Pabitra
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 933 (1-3) : 126 - 131
  • [3] Electrochemical behavior of metal complexes with a N2S2 ligand
    Ramirez-Delgado, Vanessa
    Manzanera-Estarda, Mayra
    Carlos Garcia-Ramos, Juan
    Felipe Hernandez-Ayala, Luis
    Flores-Alamo, Marcos
    Ruiz-Azuara, Lena
    Ortiz-Frade, Luis
    NEW PROCESSES AND MATERIALS BASED ON ELECTROCHEMICAL CONCEPTS AT THE MICROSCOPIC LEVEL SYMPOSIUM, MICROECHEM 2013, 2014, 12 : 115 - 120
  • [4] NEW TCO (N2S2) COMPLEXES AS POTENTIAL IMAGING AGENTS
    OYA, S
    BRADSHAW, J
    CHUMPRADIT, S
    ZHUANG, ZP
    FREDERICK, D
    KUNG, HF
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 246 - MEDI
  • [5] Copper(II) complexes of tetradentate N2S2 donor sets: Synthesis, crystal structure characterization and reactivity
    Sarkar, S.
    Patra, A.
    Drew, M. G. B.
    Zangrando, E.
    Chattopadhyay, P.
    POLYHEDRON, 2009, 28 (01) : 1 - 6
  • [6] GALLIUM AND INDIUM COMPLEXES OF BIS(AMINOTHIOL)(N2S2) LIGANDS
    ZHENG, YY
    SALUJA, S
    YAP, G
    RHEINGOLD, A
    FRANCESCONI, LC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 509 - INOR
  • [7] NI(II) COMPLEXES OF VERSATILE N2S2 TETRADENTATE LIGANDS
    BEREMAN, RD
    DORFMAN, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1981, 182 (AUG): : 68 - INOR
  • [8] Gallium and indium complexes of bis(amino thiol) (N2S2) ligands
    Zheng, YY
    Saluja, S
    Yap, GPA
    Blumenstein, M
    Rheingold, AL
    Francesconi, LC
    INORGANIC CHEMISTRY, 1996, 35 (23) : 6656 - 6666
  • [9] Proton affinity studies of nickel N2S2 complexes and control of aggregation
    Nicholas A. Arnet
    Nattamai Bhuvanesh
    Marcetta Y. Darensbourg
    JBIC Journal of Biological Inorganic Chemistry, 2019, 24 : 909 - 917
  • [10] NEW TC-99 COMPLEXES BASED ON N2S2 LIGANDS
    KUNG, HF
    GUO, YZ
    YU, CC
    MACH, RH
    EFANGE, SMN
    BLAU, M
    JOURNAL OF NUCLEAR MEDICINE, 1986, 27 (06) : 1051 - 1051
12345