Solvent-free reaction of 4-amino-1,2,4-triazole-3-thioles with 1,2,4-triazine-5-carbonitriles

被引：0
|
作者：
Shtaitz, Ya. K. [1 ]
Ladin, E. D. [1 ,2 ]
Il'inykh, E. S. [3 ]
Starnovskaya, E. S. [1 ,2 ]
Kopchuk, D. S. [1 ,2 ]
Zyryanov, G. V. [1 ,2 ]
Rusinov, V. L. [1 ,2 ]
机构：
[1] Ural Fed Univ, Dept Organ & Biomol Chem, 19 Ul Mira, Ekaterinburg 620002, Russia
[2] Russian Acad Sci, I Ya Postovsky Inst Organ Synth, Ural Branch, 22 Ul S Kovalevskoy, Ekaterinburg 620990, Russia
[3] South Ural State Univ, 76 Prosp Lenina, Chelyabinsk 454080, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 12期
基金：
俄罗斯科学基金会;
关键词：
1,2,4-triazine-5-carbonitriles; 4-amino-1,2,4-triazole-3-thiols; nucleo-philic ipso-substitution; 5-amino-1,2,4-triazines; 1,2,4-TRIAZINE 4-OXIDES; TRANSFORMATIONS; SUBSTITUTION; S-N(H);
D O I：
10.1007/s11172-023-4105-6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A solvent-free reaction of 5-cyano-1,2,4-triazines with 4-amino-1,2,4-triazole-3-thiols was studied. The reactions take place only at elevated temperature (200 degrees C) and unexpectedly produce 5-amino-1,2,4-triazines in the yields up to 36%.
引用
收藏
页码：2948 / 2952
页数：5
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