Solvent-free reaction of 4-amino-1,2,4-triazole-3-thioles with 1,2,4-triazine-5-carbonitriles

被引：0
|
作者：
Shtaitz, Ya. K. [1 ]
Ladin, E. D. [1 ,2 ]
Il'inykh, E. S. [3 ]
Starnovskaya, E. S. [1 ,2 ]
Kopchuk, D. S. [1 ,2 ]
Zyryanov, G. V. [1 ,2 ]
Rusinov, V. L. [1 ,2 ]
机构：
[1] Ural Fed Univ, Dept Organ & Biomol Chem, 19 Ul Mira, Ekaterinburg 620002, Russia
[2] Russian Acad Sci, I Ya Postovsky Inst Organ Synth, Ural Branch, 22 Ul S Kovalevskoy, Ekaterinburg 620990, Russia
[3] South Ural State Univ, 76 Prosp Lenina, Chelyabinsk 454080, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 12期
基金：
俄罗斯科学基金会;
关键词：
1,2,4-triazine-5-carbonitriles; 4-amino-1,2,4-triazole-3-thiols; nucleo-philic ipso-substitution; 5-amino-1,2,4-triazines; 1,2,4-TRIAZINE 4-OXIDES; TRANSFORMATIONS; SUBSTITUTION; S-N(H);
D O I：
10.1007/s11172-023-4105-6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A solvent-free reaction of 5-cyano-1,2,4-triazines with 4-amino-1,2,4-triazole-3-thiols was studied. The reactions take place only at elevated temperature (200 degrees C) and unexpectedly produce 5-amino-1,2,4-triazines in the yields up to 36%.
引用
收藏
页码：2948 / 2952
页数：5
相关论文
共 50 条
  • [1] Solvent-free reaction of 4-amino-1,2,4-triazole-3-thioles with 1,2,4-triazine-5-carbonitriles
    Ya. K. Shtaitz
    E. D. Ladin
    E. S. Il’inykh
    E. S. Starnovskaya
    D. S. Kopchuk
    G. V. Zyryanov
    V. L. Rusinov
    Russian Chemical Bulletin, 2023, 72 : 2948 - 2952
  • [2] Solvent-Free Reaction of 3,6-Diaryl-1,2,4-triazine-5-carbonitriles with 2-Amino-4-aryloxazoles
    Rammohan, A.
    Shtaitz, Ya. K.
    Ladin, E. D.
    Krinochkin, A. P.
    Slepukhin, P. A.
    Sharutin, V. V.
    Sharafieva, E. R.
    Pospelova, T. A.
    Kopchuk, D. S.
    Zyryanov, G. V.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2023, 93 (02) : 263 - 267
  • [3] Solvent-Free Reaction of 3,6-Diaryl-1,2,4-triazine-5-carbonitriles with 2-Amino-4-aryloxazoles
    A. Rammohan
    Ya. K. Shtaitz
    E. D. Ladin
    A. P. Krinochkin
    P. A. Slepukhin
    V. V. Sharutin
    E. R. Sharafieva
    T. A. Pospelova
    D. S. Kopchuk
    G. V. Zyryanov
    Russian Journal of General Chemistry, 2023, 93 : 263 - 267
  • [4] Reaction of 3-Amino-5H- and 3-Amino-5-sulfanyl-1,2,4-triazoles with 1,2,4-Triazine-5-carbonitriles
    A. P. Krinochkin
    M. R. Guda
    D. S. Kopchuk
    Ya. K. Shtaitz
    K. V. Savateev
    E. N. Ulomsky
    G. V. Zyryanov
    V. L. Rusinov
    O. N. Chupakhin
    Russian Journal of Organic Chemistry, 2022, 58 : 188 - 191
  • [5] Reaction of 3-Amino-5H- and 3-Amino-5-sulfanyl-1,2,4-triazoles with 1,2,4-Triazine-5-carbonitriles
    Krinochkin, A. P.
    Guda, M. R.
    Kopchuk, D. S.
    Shtaitz, Ya. K.
    Savateev, K. V.
    Ulomsky, E. N.
    Zyryanov, G. V.
    Rusinov, V. L.
    Chupakhin, O. N.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 58 (02) : 188 - 191
  • [6] Interaction of 2-Amino-1,3,4-thiadiazoles with 1,2,4-Triazine-5-carbonitriles
    A. P. Krinochkin
    Ya. K. Shtaitz
    E. A. Kudryashova
    E. D. Ladin
    D. S. Kopchuk
    G. V. Zyryanov
    Yu. M. Shafran
    E. V. Nosova
    O. N. Chupakhin
    Doklady Chemistry, 2022, 504 : 79 - 82
  • [7] Interaction of 2-Amino-1,3,4-thiadiazoles with 1,2,4-Triazine-5-carbonitriles
    Krinochkin, A. P.
    Shtaitz, Ya K.
    Kudryashova, E. A.
    Ladin, E. D.
    Kopchuk, D. S.
    Zyryanov, G., V
    Shafran, Yu M.
    Nosova, E., V
    Chupakhin, O. N.
    DOKLADY CHEMISTRY, 2022, 504 (01) : 79 - 82
  • [8] 4-Amino-1,2,4,-triazole (1,3,4-triazole, 1-amino-)
    Allen, CFH
    Bell, A
    ORGANIC SYNTHESES, 1944, 24 : 12 - 14
  • [9] Reaction of 1,2,4-Triazine-5-carbonitriles with 5-[(2-Hydroxyethyl)sulfanyl]- and 5-{[2-(2-Hydroxyethoxy)-ethyl]sulfanyl}-3-amino-1,2,4-triazoles1
    Krinochkin, A. P.
    Ladin, E. D.
    Shtaitz, Ya. K.
    Kudryashova, E. A.
    Kopchuk, D. S.
    Gorbunov, E. B.
    Shafran, Yu. M.
    Zyryanov, G. V.
    Rusinov, V. L.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 59 (11) : 1998 - 2002
  • [10] Silver(I) complexes with 1,2,4-triazole, 1-ethyl-1,2,4-triazole, 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole and 3,5-diamino-1,2,4-triazole
    Gabryszewski, M
    Wieczorek, B
    POLISH JOURNAL OF CHEMISTRY, 1998, 72 (10) : 2352 - 2355
12345