Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate

被引：0

作者：

Sakhapov, I. F. ^{[1
]}

Kagilev, A. A. ^{[1
,2
]}

Kantyukov, A. O. ^{[1
,2
]}

Mikhailov, I. K. ^{[1
,2
]}

Sof'icheva, O. S. ^{[1
]}

Islamov, D. R. ^{[3
]}

Gafurov, Z. N. ^{[1
]}

Yakhvarov, D. G. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, FRC Kazan Sci Ctr, Kazan 420088, Russia

[2] Kazan Fed Univ, Alexander Butlerov Inst Chem, Kazan 420008, Russia

[3] Russian Acad Sci, FRC Kazan Sci Ctr, Kazan 420029, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 68卷 / 09期

关键词：

alpha-phosphino-alpha-amino acid; alpha-diphenylphosphorylglycinate; cobalt complex; X-ray diffraction; cyclic voltammetry; C-H FUNCTIONALIZATION; AMINO-ACIDS; BUILDING-BLOCKS; CATALYST;

D O I：

10.1134/S0036023623700316

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New bis-chelate cobalt(II) complex [Co(DPG)(2)(DMF)(2)] (<bold>1</bold>), where DPG is N-(2,5-bis(methoxycarbonyl)phenyl)-alpha-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of alpha-amino acid. Octahedral coordination geometry of the cobalt complex <bold>1</bold> has been determined by X-ray diffraction. Electrochemical reduction of the obtained complex has been found to be irreversible two-electron process (E-p(red)= -1.70 V vs Ag/AgNO3, 1 x 10(-2) & Mcy; in CH3CN), resulting in formation of cobalt metal adsorbed on the surface of working electrode.

引用

页码：1257 / 1262

页数：6

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