Selective Furfuryl Alcohol Production from Furfural via Bio-Electrocatalysis

被引：3

作者：

Zhan, Peng ^{[1
]}

Liu, Xiangshi ^{[2
]}

Zhu, Qian ^{[1
]}

Zhao, Hongqing ^{[1
]}

Zhang, Shiding ^{[1
]}

Zhang, Chenxi ^{[1
]}

Ren, Cong ^{[1
]}

Zhang, Jiawen ^{[1
]}

Zhang, Changwei ^{[1
]}

Cai, Di ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Natl Energy R&D Ctr Biorefinery, Beijing 100029, Peoples R China

[2] Beijing Univ Chem Technol, Coll Life Sci & Technol, Beijing 100029, Peoples R China

来源：

CATALYSTS | 2023年 / 13卷 / 01期

基金：

中国国家自然科学基金;

关键词：

bio-electrocatalysis; furfuryl alcohol; furfural reduction; Rh (III) complex; alcohol dehydrogenase; ELECTROCHEMICAL REGENERATION; NADH REGENERATION; CARBON ELECTRODE; REDUCTION; EFFICIENT; NICOTINAMIDE; ENZYMES; IMMOBILIZATION; HYDROGENATION; OXIDATION;

D O I：

10.3390/catal13010101

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic reduction of renewable furfural into furfuryl alcohol for various applications is in the ascendant. Nonetheless, the conventional chemo-catalysis hydrogenation of furfural always suffers from poor selectivity, harsh conditions, and expensive catalysts. Herein, to overcome the serious technical barriers of conventional furfuryl alcohol production, an alternative bio-electrocatalytic hydrogenation system was established under mild and neutral conditions, where the dissolved cofactor (NADH) and the alcohol dehydrogenase (ADH) participated in a tandem reaction driven by the electron from a novel Rh (III) complex fixed cathode. Under the optimized conditions, 81.5% of furfural alcohol selectivity can be realized at -0.43 V vs. RHE. This contribution presents a 'green' and promising route for the valorization of furfural and other biomass compounds.

引用

页数：10

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