A prediction model to predict the thermodynamic conditions of gas hydrates

被引:3
|
作者
Sayani, Jai Krishna Sahith [1 ]
English, Niall J. [1 ]
Khan, Muhammad Saad [2 ]
Ali, Abulhassan [3 ]
机构
[1] Univ Coll Dublin, Sch Chem & Bioproc Engn, Dublin D04 V1W8, Ireland
[2] Univ Teknol PETRONAS, CO2 Res Ctr, Seri Iskandar, Perak, Malaysia
[3] Jeddah Univ, Dept Chem Engn, Jeddah, Saudi Arabia
关键词
Gas hydrate; Thermodynamic conditions; EOS; Phase behavior; Prediction modelling; CARBON-DIOXIDE; HYDROGEN STORAGE; ALKYL CHAIN; ENERGY; MEMBRANES; STATE; CO2;
D O I
10.1016/j.chemosphere.2022.137550
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Gas Hydrate modelling has gained huge attention in the past decade due to its increase in usage for various energy as well as environmental applications at an industrial scale. As the experimental approach is highly expensive and time-consuming, modelling is the best way to predict the conditions before the actual applications at industrial scales. The commercial software currently existing uses the equation of states (EOS) to predict the thermodynamic conditions of gas hydrates. But, in certain cases, the prediction by using EOS fails to predict the hydrate conditions accurately. Therefore, there arose a need for an accurate prediction model to estimate the hydrate formation conditions. So, in this work, an accurate prediction model has been proposed to predict the thermodynamic equilibrium conditions of the gas hydrate formation. The performance of prediction accuracy for the proposed model is compared with those of the SRK equation of state and Peng Robinson (PR) Equation of state. It was observed that in most of the cases the proposed model has predicted the thermodynamic conditions more accurately than the PR and SRK equation of state. This work helps in understanding the limitations of EOS for the prediction hydrate conditions. Also, the current work helps in strengthening the conventional statistical modelling technique to predict the hydrate conditions for a broader range.
引用
收藏
页数:7
相关论文
共 50 条
  • [21] Features of Thermodynamic Conditions of the Formation and the Gas Composition in Natural Gas Hydrates Obtained in a Dispersed Medium with Aqueous Calcium Chloride
    Portnyagin, A. S.
    Ivanova, I. K.
    Kalacheva, L. P.
    Ivanov, V. K.
    Portnyagina, V. V.
    CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS, 2024, 60 (04) : 855 - 862
  • [22] Thermodynamic Stability of Mixed Gas Hydrates Containing Hydrogen
    Hashimoto, Shunsuke
    Sugahara, Takeshi
    Moritoki, Masato
    Sato, Hiroshi
    Ohgaki, Kazunari
    JOINT 21ST AIRAPT AND 45TH EHPRG INTERNATIONAL CONFERENCE ON HIGH PRESSURE SCIENCE AND TECHNOLOGY, 2008, 121
  • [23] Types of gas hydrates in marine environments and their thermodynamic characteristics
    Chen, Duo-Fu
    Su, Zheng
    Cathles, Lawrence M.
    TERRESTRIAL ATMOSPHERIC AND OCEANIC SCIENCES, 2006, 17 (04): : 723 - 737
  • [24] Equilibrium data and thermodynamic modelling of cyclohexane gas hydrates
    Tohidi, B
    Danesh, A
    Burgass, RW
    Todd, AC
    CHEMICAL ENGINEERING SCIENCE, 1996, 51 (01) : 159 - 163
  • [25] A novel model to predict phase equilibrium state of hydrates from the relationship of gas solubility
    Jiang, Jianbing
    Jiang, Jianxun
    Mao, Jinchen
    Li, Dong
    Liu, Tuanhui
    Pan, Zhong
    FRONTIERS IN ENERGY RESEARCH, 2024, 12
  • [26] Urea as a green thermodynamic inhibitor of sII gas hydrates
    Gong, Yinghua
    Mendgaziev, Rais, I
    Hu, Wei
    Li, Yingzhou
    Li, Zhi
    Stoporev, Andrey S.
    Manakov, Andrey Yu
    Vinokurov, Vladimir A.
    Li, Tianduo
    Semenov, Anton P.
    CHEMICAL ENGINEERING JOURNAL, 2022, 429
  • [27] Thermodynamic stability conditions, methane enrichment, and gas uptake of ionic clathrate hydrates of mine ventilation air
    Du, Jianwei
    Li, Huijuan
    Wang, Liguang
    CHEMICAL ENGINEERING JOURNAL, 2015, 273 : 75 - 81
  • [28] Novel Thermokinetic Model for Gas Hydrates: Experimental Validation at Diverse Geological Conditions
    Patankar, Shivani M.
    Palodkar, Avinash V.
    Jana, Amiya K. .
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (50) : 18282 - 18296
  • [29] A model to predict the thermodynamic stability of abiotic methane-hydrogen binary hydrates in a marine serpentinization environment
    Zhu, Zhiwei
    Cao, Yuncheng
    Zheng, Zihan
    Wu, Nengyou
    Chen, Duofu
    FRONTIERS IN MARINE SCIENCE, 2023, 10
  • [30] A THERMODYNAMIC MODEL FOR STRUCTURE-H HYDRATES
    MEHTA, AP
    SLOAN, ED
    AICHE JOURNAL, 1994, 40 (02) : 312 - 320