Electrochemical Borylation of Electron-Deficient Alkenes and Allenoates

被引：7

作者：

Aelterman, Maude ^{[1
]}

Jubault, Philippe ^{[1
]}

Poisson, Thomas ^{[1
]}

机构：

[1] Normandie Univ, INSA Rouen, UNIROUEN, COBRA,UMR 6014,CNRS, F-76000 Rouen, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 26卷 / 17期

关键词：

allenoates; borylation; electrochemistry; electron-deficient alkenes; synthetic method; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; CATALYZED BETA-BORATION; B BOND FORMATION; HYDROBORATION; ACTIVATION; CHEMISTRY; REAGENTS; TERTIARY; COMPLEX; AMIDE;

D O I：

10.1002/ejoc.202300063

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrochemical borylation of electro-deficient alkenes and allenoates is disclosed. In an undivided cell and under galvanostatic conditions a panel of Michael acceptor and allenoates was readily reacted. The reaction offered an access to versatile borylated building blocks in good to excellent yields (20 examples, 47 % to 91 % yields). A plausible reaction mechanism, based on the literature precedent was suggested.

引用

页数：4

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