This paper proposes a wake-excited magnetically coupled piezoelectric energy harvester (WMPEH) to realize the self-powered function of microelectronic devices in a fluid environment. The WMPEH consists of a fixed column, a vibrating column, magnets, and a piezoelectric composite beam. A series of water tunnel experiments are conducted to prove the usefulness of wake excitation and magnetic coupling, and how it positively or negatively affects the harvester's efficacy. Different fixed and vibrating column diameters and the distance between the two columns affect the performance of the WMPEH. The influence of the wake excitation force generated by the fixed columns with diameters of 5 mm, 10 mm and 15 mm on the vibrating column is analyzed respectively in the experiment. The vibrating column diameter is D, and four different distances are considered, namely 2D, 3D, 4D, and 5D. The results show that the maximum output voltage of WMPEH is increased by 1.96 and 1.34 times, respectively, compared with that of magnetically coupled piezoelectric energy harvester (MPEH) and conven-tional piezoelectric energy harvester (PEH). Furthermore, increasing the fixed column diameter leads to a decrease in the output voltage of WMPEH in the case of the same vibrating column diameter. Increasing the diameter and mass of the vibrating column for a specific fixed column diameter can enhance the harvester's performance. The maximum output voltage density of the WMPEH is 75.56 V/cm3 when the vibrating column diameter, the fixed column diameter and the distance between the two columns are 20 mm, 5 mm, and 2D, respectively. This proposed design can provide the groundwork to promote the performance of the conventional PEH, further enabling the realization of underwater self-powered systems.