Dynamical diffraction of high-energy electrons by light-atom structures: a multiple forward scattering interpretation

被引:0
|
作者
Drevon, Tarik R. [1 ,2 ]
Waterman, David G. [1 ,2 ]
Krissinel, Eugene [1 ,2 ]
机构
[1] STFC, Rutherford Appleton Lab, Didcot OX11 0FA, Oxon, England
[2] Rutherford Appleton Lab, CCP4, Res Complex Harwell, Didcot OX11 0FA, Oxon, England
基金
英国生物技术与生命科学研究理事会;
关键词
high-energy electron diffraction; T-matrix; multiple scattering; independent atom approximation; ELECTROMAGNETIC SCATTERING; INELASTIC-SCATTERING; LINEAR-ARRAY; CRYSTALS; WAVE;
D O I
10.1107/S2053273322011779
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Because of the strong electron-atom interaction, the kinematic theory of diffraction cannot be used to describe the scattering of electrons by an assembly of atoms due to the strong dynamical diffraction that needs to be taken into account. In this paper, the scattering of high-energy electrons by a regular array of light atoms is solved exactly by applying the T-matrix formalism to the corresponding Schrodinger's equation in spherical coordinates. The independent atom model is used, where each atom is represented by a sphere with an effective constant potential. The validity of the forward scattering approximation and the phase grating approximation, assumed by the popular multislice method, is discussed, and an alternative interpretation of multiple scattering is proposed and compared with existing interpretations.
引用
收藏
页码:180 / 191
页数:12
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