Pd-Catalyzed Photochemical Alkylative Functionalization of C=C and C=N Bonds

被引：11
|
作者：
Upreti, Ganesh Chandra [1 ]
Singh, Tavinder [1 ]
Khanna, Kirti [1 ]
Singh, Anand [1 ,2 ]
机构：
[1] IIT Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India
[2] IIT Kanpur, Dept Sustainable Energy Engn, Kanpur 208016, Uttar Pradesh, India
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 07期
关键词：
HECK REACTION; HANTZSCH 1,4-DIHYDROPYRIDINES; RADICAL CYCLIZATION; CASCADE; HALIDES; COMPLEXES;
D O I：
10.1021/acs.joc.2c03028
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The development of excited-state palladium-catalyzed alkylative cyclization of acrylamides and the alkylation of quinoxalinones is described. The application of a variety of primary, secondary, and tertiary unactivated alkyl halides as alkyl radical precursors and the use of a simple catalyst system are the highlights of this reactivity manifold. The reactions exhibit wide scope, occur under mild conditions, and furnish the products in excellent yields.
引用
收藏
页码：4422 / 4433
页数：12
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