Crystal structure of Ag3Dy2(NO3)9 and quantitative comparison to isotypic compounds

被引：0
|
作者：
Klein, Wilhelm [1 ]
机构：
[1] Tech Univ Munich, Sch Nat Sci, Dept Chem, Lichtenbergstr 4, D-85747 Garching, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; dysprosium; silver; nitrate; BOND-VALENCE PARAMETERS; M = LA; POTASSIUM-NITRATE; LANTHANIDES;
D O I：
10.1107/S2056989023004747
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Single crystals of Ag3Dy2(NO3)(9) (trisilver didysprosium nonanitrate) were obtained from a mixture of AgNO3 and Dy(NO3)(3)center dot 5 H2O. The new compound crystallizes in space group P4(1)32 (No. 213) with a = 13.2004 (4) angstrom, V = 2300.2 (2) angstrom(3), Z = 4. The Ag and Dy cations are coordinated by five and six bidentate nitrate anions, respectively. Ag3Dy2(NO3)(9) is isostructural to several compounds that include alkali metals or ammonium and lanthanide cations, but silver and dysprosium are included for the first time and feature the smallest ion radii observed for this structure type to date. Crystal structures of isotypic compounds are compared.
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页码：600 / +
页数：9
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