Exploring the free-energy landscape of a rotating superfluid

被引:1
|
作者
Cleary, Andrew [1 ]
Page, Jacob [1 ]
机构
[1] Univ Edinburgh, Sch Math, Edinburgh EH9 3FD, Scotland
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1063/5.0163803
中图分类号
O29 [应用数学];
学科分类号
070104 ;
摘要
The equilibrium state of a superfluid in a rotating cylindrical vessel is a vortex crystal-an array of vortex lines, which is stationary in the rotating frame. Experimental realizations of this behavior typically show a sequence of transient states before the free-energy-minimizing configuration is reached. Motivated by these observations, we construct a new method for a systematic exploration of the free-energy landscape via gradient-based optimization of a scalar loss function. Our approach is inspired by the pioneering numerical work of Campbell and Ziff [Phys. Rev. B. 20, 1886 (1979)] and makes use of automatic differentiation, which crucially allows us to include entire solution trajectories in the loss. We first use the method to converge thousands of low free-energy relative equilibria in the unbounded domain for vortex numbers in the range 10 <= N <= 30, which reveals an extremely dense set of mostly saddle-like solutions. As part of this search, we discover new continuous families of relative equilibria, which are often global minimizers of free energy. These continuous families all consist of crystals arranged in a double-ring configuration, and we assess which state from the family is most likely to be observed experimentally by computing energy-minimizing pathways from nearby local minima-identifying a common entry point into the family. The continuous families become discrete sets of equal-energy solutions when the wall is introduced in the problem. Finally, we develop an approach to compute homoclinic orbits and use it to examine the dynamics in the vicinity of the minimizing state by converging connections for low-energy saddles.(c) 2023 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license
引用
收藏
页数:17
相关论文
共 50 条
  • [31] The free-energy landscape of single-molecule polymer crystals
    Larini, L.
    Leporini, D.
    PHILOSOPHICAL MAGAZINE, 2007, 87 (3-5) : 411 - 415
  • [32] MOLECULAR MODELLING STUDY OF FREE-ENERGY LANDSCAPE OF OXYTOCIN AND ATOSIBAN
    Spiwok, V.
    Jakusch, M.
    Pospisil, P.
    Folkers, G.
    Pliska, V.
    JOURNAL OF PEPTIDE SCIENCE, 2004, 10 : 232 - 232
  • [33] Reconstructing the free-energy landscape of a mechanically unfolded model protein
    Imparato, Alberto
    Luccioli, Stefano
    Torcini, Alessandro
    PHYSICAL REVIEW LETTERS, 2007, 99 (16)
  • [34] Free-energy landscape of protein oligomerization from atomistic simulations
    Barducci, Alessandro
    Bonomi, Massimiliano
    Prakash, Meher K.
    Parrinello, Michele
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2013, 110 (49) : E4708 - E4713
  • [35] Free-Energy Landscape and Characteristic Forces for the Initiation of DNA Unzipping
    Mentes, Ahmet
    Florescu, Ana Maria
    Brunk, Elizabeth
    Wereszczynski, Jeff
    Joyeux, Marc
    Andricioaei, Ioan
    BIOPHYSICAL JOURNAL, 2015, 108 (07) : 1727 - 1738
  • [36] Role of Small Oligomers on the Amyloidogenic Aggregation Free-Energy Landscape
    He, Xianglan
    Giurleo, Jason T.
    Talaga, David S.
    JOURNAL OF MOLECULAR BIOLOGY, 2010, 395 (01) : 134 - 154
  • [37] SINGULAR GRADIENT FREE-ENERGY OF SUPERFLUID HE-3-A AT T=0
    GARG, A
    PHYSICAL REVIEW B, 1987, 36 (13): : 6794 - 6798
  • [38] Entropic control of the free-energy landscape of an archetypal biomolecular machine
    Ray, Korak Kumar
    Kinz-Thompson, Colin D.
    Fei, Jingyi
    Wang, Bin
    Lin, Qiao
    Gonzalez, Ruben L.
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2023, 120 (21)
  • [39] Free-Energy Landscape of the Helical Wrapping of a Carbon Nanotube by a Polysaccharide
    Liu, Yingzhe
    Chipot, Christophe
    Shao, Xueguang
    Cai, Wensheng
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (05): : 1851 - 1856
  • [40] Derivation of the Invariant Free-Energy Landscape Based on Langevin Dynamics
    Nakamura, Takenobu
    PHYSICAL REVIEW LETTERS, 2024, 132 (13)