Diiodo-BODIPY Sensitizing of the [Mo3S13]2-Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix

被引：10

作者：

Costabel, Daniel ^{[1
]}

Nabiyan, Afshin ^{[1
]}

Chettri, Avinash ^{[2
,3
]}

Jacobi, Franz ^{[1
]}

Heiland, Magdalena ^{[4
]}

Guthmuller, Julien ^{[5
]}

Kupfer, Stephan ^{[2
]}

Waechtler, Maria ^{[2
,3
,6
,7
]}

Dietzek-Ivansic, Benjamin ^{[2
,3
,8
,9
]}

Streb, Carsten ^{[4
,10
]}

Schacher, Felix H. ^{[1
,8
,9
]}

Peneva, Kalina ^{[1
,8
,9
]}

机构：

[1] Friedrich Schiller Univ Jena, Inst Organ Chem & Macromol Chem, D-07743 Jena, Germany

[2] Friedrich Schiller Univ Jena, Inst Phys Chem, D-07743 Jena, Germany

[3] Leibniz Inst Photon Technol Jena, D-07745 Jena, Germany

[4] Ulm Univ, Inst Inorgan Chem 1, D-89081 Ulm, Germany

[5] Gdansk Univ Technol, Inst Phys & Appl Comp Sci, Fac Appl Phys & Math, PL-80233 Gdansk, Poland

[6] RPTU Kaiserslautern Landau, Chem Dept, Erwin Schrodinger Str 52, D-67663 Kaiserslautern, Germany

[7] State Res Ctr Optimas, Erwin Schrodinger Str 52, D-67663 Kaiserslautern, Germany

[8] Friedrich Schiller Univ Jena, Ctr Energy & Environm Chem, D-07743 Jena, Germany

[9] Friedrich Schiller Univ Jena, Jena Ctr Soft Matter, D-07743 Jena, Germany

[10] Johannes Gutenberg Univ Mainz, Dept Chem, Mainz Duesbergweg 10-14, D-55128 Mainz, Germany

来源：

ACS APPLIED MATERIALS & INTERFACES | 2023年 / 15卷 / 17期

关键词：

BODIPY; hydrogen evolution; quantum chemistry; photocatalysis; thiomolybdate; TRIPLET-TRIPLET ANNIHILATION; EXCITED-STATE; ACTIVE-SITE; PHOTOSENSITIZERS; DYES; THIOMOLYBDATE; COMPLEXES; DERIVATIVES; CATALYSIS;

D O I：

10.1021/acsami.2c18529

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We report on a photocatalytic setup that utilizes the organic photosensitizer (PS) diiodo-BODIPY and the non-precious-metal-based hydro-gen evolution reaction (HER) catalyst (NH4)2[Mo3S13] together with a polyampholytic unimolecular matrix poly(dehydroalanine)-graft-poly(ethylene glycol) (PDha-g-PEG) in aqueous media. The system shows exceptionally high performance with turnover numbers (TON > 7300) and turnover frequencies (TOF > 450 h-1) that are typical for noble-metal-containing systems. Excited-state absorption spectra reveal the formation of a long-lived triplet state of the PS in both aqueous and organic media. The system is a blueprint for developing noble-metal-free HER in water. Component optimization, e.g., by modification of the meso substituent of the PS and the composition of the HER catalyst, is further possible.

引用

页码：20833 / 20842

页数：10

共 50 条

[31] Hierarchical ZnIn2S4/MoSe2 Nanoarchitectures for Efficient Noble-Metal-Free Photocatalytic Hydrogen Evolution under Visible Light
Zeng, Deqian
Xiao, Lang
Ong, Wee-Jun
Wu, Pengyuan
Zheng, Hongfei
Chen, Yuanzhi
Peng, Dong-Liang
CHEMSUSCHEM, 2017, 10 (22) : 4624 - 4631
[32] Noble metal-free NiCo2S4/CN sheet-on-sheet heterostructure for highly efficient visible-light-driven photocatalytic hydrogen evolution
Jiang, Kerui
Iqbal, Waheed
Yang, Bo
Rauf, Muhammad
Ali, Imran
Lu, Xiaoying
Mao, Yanping
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 853
[33] CoNi Bimetal Cocatalyst Modifying a Hierarchical ZnIn2S4 Nanosheet-Based Microsphere Noble-Metal-Free Photocatalyst for Efficient Visible-Light-Driven Photocatalytic Hydrogen Production
Li, Zhenjiang
Wang, Xuehua
Tian, Wenli
Meng, Alan
Yang, Lina
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (24) : 20190 - 20201
[34] Constructing a noble-metal-free 0D/2D CdS/SnS2 heterojunction for efficient visible-light-driven photocatalytic pollutant degradation and hydrogen generation
Hu, Hanmei
He, Yunyun
Yu, Hong
Li, Dongcai
Sun, Mei
Feng, Yanyan
Zhang, Chuanyue
Chen, Haoran
Deng, Chonghai
NANOTECHNOLOGY, 2023, 34 (50)
[35] A novel noble-metal-free Mo2C-In2S3 heterojunction photocatalyst with efficient charge separation for enhanced photocatalytic H2 evolution under visible light
Ma, Xiaohui
Ren, Chaojun
Li, Hongda
Liu, Xintong
Li, Xinyang
Han, Kun
Li, Wenjun
Zhan, Yifei
Khan, Ajmal
Chang, Zhidong
Sun, Changyan
Zhou, Hualei
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 582 : 488 - 495
[36] Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production Using Robust Noble-Metal-Free Zn0.5Cd0.5S@Graphene Composites Decorated with MoS2 Nanosheets
Madhusudan, Puttaswamy
Shi, Run
Chandrashekar, Bananakere Nanjegowda
Xiang, Shengling
Smitha, Ankanahalli Shankaregowda
Wang, Weijun
Zhang, Haichao
Zhang, Xian
Amini, Abbas
Cheng, Chun
ADVANCED MATERIALS INTERFACES, 2020, 7 (12)
[37] Highly efficient noble-metal-free NiS/rGO/Cd0.3Zn0.7S nanorods in visible-light-driven H2 evolution with enhanced surface photoinduced charge transfer
Wang, Xiaohao
Li, Lingfeng
Gu, Huajun
Zhang, Huihui
Zhang, Juhua
Zhang, Quan
Dai, Wei-Lin
APPLIED SURFACE SCIENCE, 2022, 574
[38] Rational design of ternary NiS/CQDs/ZnIn2S4 nanocomposites as efficient noble-metal-free photocatalyst for hydrogen evolution under visible light
Wang, Bingqing
Ding, Yao
Deng, Zirong
Li, Zhaohui
CHINESE JOURNAL OF CATALYSIS, 2019, 40 (03) : 335 - 342
[39] Noble-metal-free g-C3N4/Ni(dmgH)2 composite for efficient photocatalytic hydrogen evolution under visible light irradiation
Cao, Shao-Wen
Yuan, Yu-Peng
Barber, James
Loo, Say Chye Joachim
Xue, Can
APPLIED SURFACE SCIENCE, 2014, 319 : 344 - 349
[40] Noble-metal-free MnS/In2S3 composite as highly efficient visible light driven photocatalyst for H2 production from H2S
Dan, Meng
Zhang, Qian
Yu, Shan
Prakash, Arvind
Lin, Yuanhua
Zhou, Ying
APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 217 : 530 - 539

← 1 2 3 4 5 →