Kinetics and Mechanism of Electrochemical Reactions Occurring during the Chromium Electrodeposition from Electrolytes Based on Cr(III) Compounds: A Literature Review

被引：5

作者：

Protsenko, V. S. ^{[1
]}

机构：

[1] Ukrainian State Univ Chem Technol, Gagarin Ave 8, Dnipro 49005, Ukraine

来源：

REACTIONS | 2023年 / 4卷 / 03期

关键词：

chromium; trivalent chromium compounds; kinetics; mechanism; electrodeposition; DEEP EUTECTIC SOLVENTS; RAY-EMISSION SPECTROSCOPY; IONIC LIQUID ANALOGS; CR-C LAYER; TRIVALENT CHROMIUM; FORMIC-ACID; DIMENSIONAL ANALYSIS; PHYSICOCHEMICAL PROPERTIES; REDUCTION-MECHANISM; CORROSION BEHAVIOR;

D O I：

10.3390/reactions4030024

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A literature review was conducted to examine the current understanding of the kinetics and mechanism of electrochemical reactions occurring during the electrodeposition of chromium coatings from electrolytes based on trivalent chromium compounds. The research in this scientific field is crucial, as it addresses the pressing need for an alternative to chromium plating processes that rely on solutions containing highly toxic and harmful hexavalent chromium compounds. Numerous literature data on the kinetics and mechanism of the stepwise reduction process of Cr(III) complex ions were analyzed. The influence of various additives and surfactants on the reaction kinetics of the stepwise reduction of trivalent chromium ions was considered. Special attention was given to the kinetics of the stepwise discharge of trivalent chromium ions in ionic liquids and deep eutectic solvents.

引用

页码：398 / 419

页数：22

共 40 条

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Danilov, F. I.
Protsenko, V. S.
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PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2011, 47 (05) : 598 - 605
[22] Electrodeposition of nanocrystalline chromium coatings from Cr(III)-based electrolyte using pulsed current
F. I. Danilov
V. S. Protsenko
T. E. Butyrina
V. A. Krasinskii
A. S. Baskevich
S. C. Kwon
J. Y. Lee
Protection of Metals and Physical Chemistry of Surfaces , 2011, 47 : 598 - 605
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T. E. Butyrina
E. A. Vasil’eva
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Protection of Metals, 2006, 42 : 560 - 569
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Danilov, F. I.
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Butyrina, T. E.
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PROTECTION OF METALS, 2006, 42 (06): : 560 - 569
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[28] Estimation of the protective ability of chromium coatings deposited from sulfate and methanesulfonate electrolytes based on Cr(III)
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PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2014, 50 (05) : 672 - 678
[29] Estimation of the protective ability of chromium coatings deposited from sulfate and methanesulfonate electrolytes based on Cr(III)
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V. S. Protsenko
A. A. Kityk
Protection of Metals and Physical Chemistry of Surfaces, 2014, 50 : 672 - 678
[30] Electrodeposition of corrosion-resistant Cr–P and Cr–P–W coatings from solutions based on compounds of trivalent chromium
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A. V. Telezhkina
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Journal of Solid State Electrochemistry, 2019, 23 : 2367 - 2376

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