Cd(II)-Based Complex Constructed from 1,3,5-Tris(Carboxymethoxy)Benzene Acid Ligand for Detection of Nitroaromatic Compounds

被引：4

作者：

Chen, Ying-Jun ^{[1
]}

Zhai, Xue-Jing ^{[1
]}

Wu, Wei-Li ^{[1
]}

Li, Bo ^{[1
]}

Wang, Li-Ya ^{[1
]}

机构：

[1] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2023年 / 33卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Cd(II)-based complex; Detection; Nitroaromatic compounds; METAL-ORGANIC FRAMEWORKS; SENSOR;

D O I：

10.1007/s10904-023-02589-w

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this study, one Cd(II)-based complex, [Cd-3(L)(2)(bpy)(2)](n) (1) (L3- = 1,3,5-tris(carboxymethoxy)benzene acid), has been hydrothermally synthesized, which displayed three-dimensional (3D) supramolecular framework. The result of fluorescence quenching experiments revealed that complex 1 showed good quenching effect on nitroaromatic compounds, such as p-nitroaniline (4-NA), o-nitroaniline (2-NA), p-nitrophenol (4-NP), and the quenching effect of 4-NA were particularly significant. According to the density functional theory, the remarkable quenching efficiency of 4-NA was caused by an effective electron transport. As a fluorescent probe, Complex 1 can be used to find nitroaromatic chemicals.

引用

页码：1409 / 1414

页数：6

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