Structural Features of Pentaphenylantimony, Penta(p-tolyl)antimony, and Their Solvates with Organic Solvents

被引：0
|
作者：
Sharutin, V. V. [1 ]
Golovin, M. S. [1 ]
机构：
[1] Natl Res Univ, South Ural State Univ, Chelyabinsk, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2023年 / 49卷 / 01期
关键词：
pentaphenylantimony; penta(p-tolyl)antimony; solvate; benzene; dioxane; structure; XRD; MOLECULAR-STRUCTURE; CRYSTAL; ANTIMONY; EXCHANGE; RADII;
D O I：
10.1134/S1070328422700336
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structures of pentaphenylantimony (I), its solvates with benzene (II) and dioxane (III), and penta(p-tolyl)antimony (IV) are solved by X-ray diffraction (XRD) (CIF files CCDC nos. 2124594, 2121835, 2124972, and 2124962, respectively). The following parameters are determined from the XRD data: crystals of Ph5Sb (I): a = 10.286(3), b = 10.510(4), c = 13.590(4) angstrom; alpha = 68.29(2)degrees, beta = 79.364(14)degrees, gamma = 61.272(12)degrees; V = 1196.9(7) angstrom(3); Z = 2; solvate Ph5Sb center dot 0.5PhH (II): a = 13.165(11), b = 14.394(16), c = 15.193(13) angstrom; alpha = 90.22(3)degrees, beta = 113.71(2)degrees, gamma = 94.23(5)degrees; V = 2627(4) angstrom(3); Z = 2; solvate Ph5Sb center dot 0.5C(4)H(8)O(2) (III): a = 10.451(5), b = 10.462(4), c = 13.323(5) angstrom; alpha = 75.647(11)degrees, beta = 69.648(19)degrees, gamma = 86.300(19)degrees; V = 1322.8(9) angstrom(3); Z = 2; and p-Tol(5)Sb (IV): b = 12.084(7), c = 17.009(6) angstrom; beta = 102.934(14)degrees; V = 2899(2) angstrom(3); Z = 4. The antimony atoms in solvates II and III have a distorted trigonal bipyramidal coordination.
引用
收藏
页码：63 / 68
页数：6
相关论文
共 50 条
  • [31] Structural Properties, Cytotoxicity, and Anti-Inflammatory Activity of Silver(I) Complexes with tris(p-tolyl)Phosphine and 5-Chloro-2-Mercaptobenzothiazole
    Kyros, L.
    Kourkoumelis, N.
    Kubicki, M.
    Male, L.
    Hursthouse, M. B.
    Verginadis, I. I.
    Gouma, E.
    Karkabounas, S.
    Charalabopoulos, K.
    Hadjikakou, S. K.
    BIOINORGANIC CHEMISTRY AND APPLICATIONS, 2010, 2010
  • [32] Ferromagnetic dimer of pi-conjugated organic free radicals 9,9-bis(p-tolyl)-9,10-dihydroacridin-10-yloxyl
    Imachi, R
    Ishida, T
    Suzuki, M
    Yasui, M
    Iwasaki, F
    Nogami, T
    CHEMISTRY LETTERS, 1997, (08) : 743 - 744
  • [33] Structural consequences of hindered rotation of tolyl substituent in 2,2,4,4,6,6-hexamethyl-1,3,5-tritolylcyclotrisilazanes.: Crystal structures of o-, m- and p-tolyl derivatives
    Glówka, ML
    Olczak, A
    Martynowski, D
    Kozlowska, K
    Kulpinski, J
    JOURNAL OF MOLECULAR STRUCTURE, 2002, 613 (1-3) : 145 - 151
  • [34] PREPARATION AND CRYSTAL-STRUCTURES OF 5 ORGANOANTIMONY HALIDES - (P-TOLYL)ANTIMONY(III) DICHLORIDE AND DIBROMIDE, DIPHENYLANTIMONY(III) BROMIDE, (BIPHENYL-2,2'-DIYL)ANTIMONY(III) CHLORIDE AND BIS-(2'-CHLOROBIPHENYL-2-YL)ANTIMONY(V) TRICHLORIDE
    MILLINGTON, PL
    SOWERBY, DB
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 480 (1-2) : 227 - 234
  • [35] 63Cu NQR and structural studies of complexes formed between Cu(I) halides and tris(o-methoxyphenyl)- or tris(p-tolyl)phosphine ligands
    Ramaprabhu, S
    Amstutz, N
    Lucken, EAC
    Bernardinelli, G
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1998, 53 (6-7): : 625 - 629
  • [36] Structure, Z′=2 Crystal Packing Features of 3-(2-Chlorobenzylidene)-5-(p-tolyl)furan-2(3H)-one
    Grinev, Vyacheslav S.
    Mayorova, Oksana A.
    Anis'kova, Tatyana V.
    Tikhomolova, Alexandra S.
    Yegorova, Alevtina Yu.
    MOLECULES, 2021, 26 (08):
  • [37] Researches on separable organic oxides bis-(p-tolyl)-I I'-diphenyl-3 3'-dimethyl-5 5'-ruben its separable oxide
    Dufraissb, C
    Monier, JA
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES, 1933, 196 : 1327 - 1329
  • [38] Spectral and structural density functional theory on 4-ethyl and 4-(p-tolyl)-1-(pyridin-2-yl)thiosemicarbazides and their Pd(II) complexes
    Abdel-Rhman, Mohamed H.
    Hassanian, Mohamed M.
    El-Asmy, Ahmed A.
    JOURNAL OF MOLECULAR STRUCTURE, 2012, 1019 : 110 - 119
  • [39] Structural relationships between o-, m- and p-tolyl substituted R3EI2 (E = As, P) and [(R3E)AuX] (E = As, P; X = Cl, Br, I)
    Barnes, Nicholas A.
    Flower, Kevin R.
    Godfrey, Stephen M.
    Hurst, Paul A.
    Khan, Rana Z.
    Pritchard, Robin G.
    CRYSTENGCOMM, 2010, 12 (12): : 4240 - 4251
  • [40] Structural, spectral, DFT and biological studies of (E)-3-(2-(2-hydroxybenzylidene)hydrazinyl)-3-oxo-N-(p-tolyl)propanamide complexes
    Abo-Zeid, S.M., 1600, Elsevier B.V., Netherlands (1075):
12345