Anode corrosion in aqueous Zn metal batteries

被引：204
|
作者：
Cai, Zhao [1 ,2 ]
Wang, Jindi [1 ,3 ]
Sun, Yongming [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430074, Peoples R China
[2] China Univ Geosci Wuhan, Fac Mat Sci & Chem, Wuhan 430074, Peoples R China
[3] Yancheng Teachers Univ, Inst New Energy Chem Storage & Power Sources, Coll Appl Chem & Environm Engn, Yancheng 224000, Peoples R China
来源：
ESCIENCE | 2023年 / 3卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Aqueous batteries; Zn metal anode; Chemical oxidation; Electrochemical hydrogen evolution; Corrosion mechanism; Surface protection; ZINC-ION BATTERIES; CHALLENGES; STRATEGIES; ELECTROLYTES; INTERFACE; INSIGHT;
D O I：
10.1016/j.esci.2023.100093
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Given their low cost and intrinsic safety, aqueous Zn metal batteries (AZMBs) are drawing increasing attention in the field of smart grids and large-scale energy storage. However, the Zn metal anode in aqueous electrolyte suffers from a critical issue, corrosion, which must be fully addressed before the practical implementation of AZMBs. In this perspective, the mechanisms of aqueous Zn metal anode corrosion in both alkaline and neutral electrolytes are compared and discussed. The methods for studying the corrosion processes and the strategies for Zn corrosion protection in AZMBs are also summarized. Finally, some expectations about potential research directions for making corrosion-resistant AZMBs a commercial reality are provided.
引用
收藏
页数：12
相关论文
共 50 条
  • [31] Suppression of Dendrite Formation and Corrosion on Zinc Anode of Secondary Aqueous Batteries
    Sun, Kyung E. K.
    Hoang, Tuan K. A.
    The Nam Long Doan
    Zhu, Yan Yu Xiao
    Tian, Ye
    Chen, P.
    ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (11) : 9681 - 9687
  • [32] Solvation Structure Design for Aqueous Zn Metal Batteries
    Cao, Longsheng
    Li, Dan
    Hu, Enyuan
    Xu, Jijian
    Deng, Tao
    Ma, Lin
    Wang, Yi
    Yang, Xiao-Qing
    Wang, Chunsheng
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (51) : 21404 - 21409
  • [33] High ionic conductive protection layer on Zn metal anode for enhanced aqueous zinc-ion batteries
    Liu, Xianyu
    Lu, Qiongqiong
    Yang, Aikai
    Qian, Yitai
    CHINESE CHEMICAL LETTERS, 2023, 34 (06)
  • [34] A low concentration electrolyte additive for constructing solid-electrolyte interphase on a Zn metal anode for aqueous batteries
    Zhang, Guoli
    Zhu, Jiaqi
    Wang, Kuo
    Li, Qianrui
    Fu, Wenchao
    Liu, Xiao-Xia
    Sun, Xiaoqi
    CHEMICAL COMMUNICATIONS, 2024, 60 (10) : 1317 - 1320
  • [35] Working Aqueous Zn Metal Batteries at 100?C
    Wang, Jiawei
    Yang, Yan
    Wang, Yingyu
    Dong, Shuai
    Cheng, Liwei
    Li, Yanmei
    Wang, Zhenya
    Trabzon, Levent
    Wang, Hua
    ACS NANO, 2022, 16 (10) : 15770 - 15778
  • [36] Comprehensive protection of Zn metal anode via caprolactam towards highly stable aqueous zinc ions batteries
    Yin, Junyi
    Li, Mingyan
    Feng, Xiang
    Cui, Tianyi
    Sun, Weiyu
    Wang, Minghui
    Shi, Weichen
    Ding, Shujiang
    Cheng, Yonghong
    Xu, Xin
    Wang, Jianhua
    JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 971
  • [37] High ionic conductive protection layer on Zn metal anode for enhanced aqueous zinc-ion batteries
    Xianyu Liu
    Qiongqiong Lu
    Aikai Yang
    Yitai Qian
    Chinese Chemical Letters, 2023, 34 (06) : 593 - 596
  • [38] Critical roles of metal-organic frameworks in improving the Zn anode in aqueous zinc-ion batteries
    Gopalakrishnan, Mohan
    Ganesan, Sunantha
    Nguyen, Mai Thanh
    Yonezawa, Tetsu
    Praserthdam, Supareak
    Pornprasertsuk, Rojana
    Kheawhom, Soorathep
    CHEMICAL ENGINEERING JOURNAL, 2023, 457
  • [39] Comprehensive protection of Zn metal anode via caprolactam towards highly stable aqueous zinc ions batteries
    Yin, Junyi
    Li, Mingyan
    Feng, Xiang
    Cui, Tianyi
    Sun, Weiyu
    Wang, Minghui
    Shi, Weichen
    Ding, Shujiang
    Cheng, Yonghong
    Xu, Xin
    Wang, Jianhua
    Journal of Alloys and Compounds, 1600, 971
  • [40] Surface Engineering on Zinc Anode for Aqueous Zinc Metal Batteries
    Peng, Huili
    Ge, Wenjing
    Ma, Xiaojian
    Jiang, Xiaolei
    Zhang, Kaiyuan
    Yang, Jian
    CHEMSUSCHEM, 2024, 17 (14)
12345