Core-shell structure and domain engineering in Bi0.5Na0.5TiO3-based ceramics with enhanced dielectric and energy storage performance

被引:19
|
作者
Xue, Guoliang [1 ]
Zhou, Xuefan [1 ]
Su, Yingchun [1 ]
Tang, Lin [1 ]
Zou, Jinzhu [1 ]
Zhang, Dou [1 ]
机构
[1] Cent South Univ, Powder Met Res Inst, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
基金
国家重点研发计划;
关键词
Bi0.5Na0.5TiO3; KTaO3; Li2CO3; Core-shell microstructure; Energy storage; Dielectric temperature stability; TEMPERATURE; BATIO3; MICROSTRUCTURE; PIEZOCERAMICS; DENSITY;
D O I
10.1016/j.jmat.2023.02.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Core-shell structured Bi0.5Na0.5TiO3-KTaO3 + x% (in mass) Li2CO3 ceramics were fabricated in this study. Increasing x from 0 to 2 leads to the decrease of sintering temperature from 1 175 degrees C to 1 020 degrees C. The limited diffusion of Ta5+ results in chemical heterogeneities and core-shell microstructures. The Ta5+depleted cores show the nanodomains (-10 nm), while the Ta5+-rich shells display the polar nanoregions (1-2 nm). From x = 0 to 1, the appearance of cores with nanodomains contributes to the increase of dielectric constant and maximum polarization, while the further addition of Li2CO3 suppresses the dielectric and polarization responses due to the reduced grain sizes and polarization coupling. The enhanced dielectric relaxation and existence of core-shell microstructure with different polarization levels help to optimize the dielectric temperature stability. The x = 2 ceramics exhibit a stable high dielectric constant -1 400 over a wide temperature range of 20-520 degrees C. More encouragingly, the ultrafine grain size and core-shell microstructure in the x = 2 ceramics greatly benefit the improvement of breakdown strength. Combined with the delayed polarization saturation and high ergodicity, a high recoverable energy density of -5.07 J/cm3 is obtained under 44 kV/mm, with a high efficiency of -85.17%. (c) 2023 The Authors. Published by Elsevier B.V. on behalf of The Chinese Ceramic Society. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
引用
收藏
页码:855 / 866
页数:12
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