Mechanochemical Rhodium-Catalyzed C-H Bond Amidation of Ferrocenes by Ball Milling

被引：0

作者：

Li, Hao ^{[1
]}

Ma, Tongtong ^{[1
]}

Wang, Yingxin ^{[1
]}

Wang, Bosen ^{[1
]}

Li, Dianjun ^{[1
]}

Yang, Jinhui ^{[1
]}

机构：

[1] Ningxia Univ, Sch Chem & Chem Engn, State Key Lab High Efficiency Utilizat Coal & Gree, Yinchuan 750021, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2023年 / 18卷 / 14期

基金：

中国国家自然科学基金;

关键词：

Mechanochemical; C-H amidation; Solvent-free; Rh-Catalyzed; Ferrocenes; SOLVENT-FREE; MILD; DIOXAZOLONES; AMINATION; OPPORTUNITIES; MECHANISM; ARYLATION; ARENES; ARYL;

D O I：

10.1002/asia.202300330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A direct protocol for Rh-catalyzed C-H amidation of ferrocenes in a ball mill using dioxazolones as the amide source under solvent-free conditions was developed. The corresponding ortho-aminated products were formed in 3 hours and the yields were up to 99% in the absence of base. This method could be a typically sustainable and environmental-friendly alternative method to traditional methodologies, with the advantages of wide substrate range, good functional group tolerance and gram-scale synthesis.

引用

页数：4

共 50 条

[31] The Mechanism of Rhodium-Catalyzed Allylic C-H Amination
Harris, Robert J.
Park, Jiyong
Nelson, Taylor A. F.
Iqbal, Nafees
Salgueiro, Daniel C.
Bacsa, John
MacBeth, Cora E.
Baik, Mu-Hyun
Blakey, Simon B.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (12) : 5842 - 5851
[32] Rhodium-Catalyzed Intramolecular C-H Silylation by Silacyclobutanes
Zhang, Qing-Wei
An, Kun
Liu, Li-Chuan
Guo, Shuangxi
Jiang, Chenran
Guo, Huifang
He, Wei
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (21) : 6319 - 6323
[33] Rhodium-Catalyzed Electrooxidative C-H Olefination of Benzamides
Zhang, Yan
Struwe, Julia
Ackermann, Lutz
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (35) : 15076 - 15080
[34] Rhodium-Catalyzed ortho-Benzoxylation of sp2 C-H Bond
Ye, Zhishi
Wang, Wenhui
Luo, Fang
Zhang, Shouhui
Cheng, Jiang
ORGANIC LETTERS, 2009, 11 (17) : 3974 - 3977
[35] Rhodium-catalyzed olefination of aryl tetrazoles via direct C-H bond activation
Wang, Liang
Wu, Wenting
Chen, Qun
He, Mingyang
ORGANIC & BIOMOLECULAR CHEMISTRY, 2014, 12 (40) : 7923 - 7926
[36] Rhodium-Catalyzed Asymmetric C-H Functionalization Reactions
Liu, Chen-Xu
Yin, Si-Yong
Zhao, Fangnuo
Yang, Hui
Feng, Zuolijun
Gu, Qing
You, Shu-Li
CHEMICAL REVIEWS, 2023, 123 (16) : 10079 - 10134
[37] A rhodium-catalyzed C-H activation/cycloisomerization tandem
Aissa, Christophe
Fuerstner, Alois
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (48) : 14836 - +
[38] Rhodium-Catalyzed Selective Olefination of Arene Esters via C-H Bond Activation
Park, Sae Hume
Kim, Ji Young
Chang, Sukbok
ORGANIC LETTERS, 2011, 13 (09) : 2372 - 2375
[39] A rhodium-catalyzed C-H activation/cycloisomerization tandem
Aissa, Christophe
Furstner, Alois
1600, American Chemical Society, Columbus, OH 43210-3337, United States (129):
[40] Rhodium-catalyzed alkylation of terephthaldialdimine with terminal alkenes via C-H bond activation
Lim, YG
Koo, BT
TETRAHEDRON LETTERS, 2005, 46 (46) : 7997 - 8001

← 1 2 3 4 5 →