4′ - (N-(2-Cyanoethyl)pyrrol-2-yl)-2,2′:6′,2"-terpyridine

被引：1

作者：

Husson, Jerome ^{[1
]}

机构：

[1] Univ Franche Comte, Inst UTINAM, UMR CNRS 6213, UFR Sci & Tech, 16 Route Gray, F-25030 Besancon, France

来源：

MOLBANK | 2023年 / 2023卷 / 03期

关键词：

Aza-Michael addition; nitrile; heterocycles; ligand; oligopyridines; COMPLEXES;

D O I：

10.3390/M1689

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation and characterization of a new multi-functionalized terpyridine molecule featuring a pyrrole heterocycle and a cyano group is described. This new compound was obtained via a KF/alumina-catalyzed Michael addition of 4 '-(pyrrol-2-yl)-2,2 ':6 ',2 ''-terpyridine into acrylonitrile. The mild reaction conditions leave the nitrile group unaltered. The title compound was fully characterized via NMR spectroscopy (H-1 and C-13) as well as via high resolution mass spectrometry and infrared spectroscopy.

引用

页数：4

共 50 条

[41] N-(2,2-Diphenylethyl)-2-(6-methoxynaphthalen-2-yl)propanamide
Manolov, Stanimir
Ivanov, Iliyan
Bojilov, Dimitar
MOLBANK, 2021, 2021 (03)
[42] N-(2-CYANOETHYL) DERIVATIVES OF MEPERIDINE, KETOBEMIDONE, AND A POTENT 6,7-BENZOMORPHAN
UWAYDAH, IM
WADDLE, MK
ROGERS, ME
JOURNAL OF MEDICINAL CHEMISTRY, 1979, 22 (07) : 889 - 890
[43] Synthesis of luminescent alkynyl gold metalaligands containing 2,2′-bipyridine-5-yl and 2,2′:6′,2"-terpyridine-4-yl donor groups
Vicente, Jose
Gil-Rubio, Juan
Barquero, Natalia
Jones, Peter G.
Bautista, Delia
ORGANOMETALLICS, 2008, 27 (04) : 646 - 659
[44] Chiral 2,2':6',2''-terpyridine ligands for metallosupramolecular chemistry .1. Synthesis of ligands and structural characterization of 4'-([(1S)-endo]-bornyloxy)-2,2':6',2''-terpyridine, 4'-([(1R)-endo]-bornyloxy)-2,2':6',2''-terpyridine, 4'-quininyl-epi-quininyl-2,2':6',2''-terpyridine, and 4'-(2,2':6',2''-terpyridinyl)-(1S)-10-camphorsulfonate
Constable, EC
Kulke, T
Neuburger, M
Zehnder, M
NEW JOURNAL OF CHEMISTRY, 1997, 21 (05) : 633 - 646
[45] Synthesis, topoisomerase I inhibition and antitumor cytotoxicity of 2,2′:6′,2"-, 2,2′:6′,3"- and 2,2:6′,4"-terpyridine derivatives
Zhao, LX
Kim, TS
Ahn, SH
Kim, TH
Kim, EK
Cho, WJ
Choi, H
Lee, CS
Kim, JA
Jeong, TC
Chang, CJ
Lee, ES
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2001, 11 (19) : 2659 - 2662
[46] Aqua[4′-(4-chlorophenyl)-2,2′:6′,2"-terpyridine]nitratocopper(II) nitrate [4′-(4-chlorophenyl)-2,2′:6′,2"-terpyridine]dinitratocopper(II) monohydrate
Zhao, Juan
Shi, Shuo
Yao, Tianming
Tan, Zhongfei
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M346 - U626
[47] A missing member in the family of chalcogenophene-substituted 2,2′:6′,2"-terpyridine: 4′-(tellurophen-2-yl)-2,2′:6′,2"-terpyridine, its Ru(II) complex and its electropolymerization as a thin film
Husson, Jerome
Abdeslam, Et Taouil
Guyard, Laurent
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2019, 855
[48] Carbaborane-functionalised 2,2′:6′,2"-terpyridine ligands for metallosupramolecular chemistry:: Syntheses, complex formation, and the crystal and molecular structures of 4′-(optho-carboranyl)-2,2′:6′,2"-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2"-terpyridine
Armspach, D
Constable, EC
Housecroft, CE
Neuburger, M
Zehnder, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) : 193 - 206
[49] Carbaborane-functionalised 2,2':6',2''-terpyridine ligands for metallosupramolecular chemistry: Syntheses, complex formation, and the crystal and molecular structures of 4'-(ortho-carboranyl)-2,2':6',2''-terpyridine and 4'-(ortho-carboranylpropoxy)-2,2':6',2''-terpyridine
J Organomet Chem, 1 (175):
[50] Gliclazide impurity F: N-[(perhydrocyclopenta[c]pyrrol-2-yl)aminocarbonyl]-o-toluenesulfonamide
Wu, Di
Wang, Xueyuan
Pang, Dongying
Su, Wei
Sun, Yan
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O446 - U1026

← 1 2 3 4 5 →