4′ - (N-(2-Cyanoethyl)pyrrol-2-yl)-2,2′:6′,2"-terpyridine

被引：1

作者：

Husson, Jerome ^{[1
]}

机构：

[1] Univ Franche Comte, Inst UTINAM, UMR CNRS 6213, UFR Sci & Tech, 16 Route Gray, F-25030 Besancon, France

来源：

MOLBANK | 2023年 / 2023卷 / 03期

关键词：

Aza-Michael addition; nitrile; heterocycles; ligand; oligopyridines; COMPLEXES;

D O I：

10.3390/M1689

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation and characterization of a new multi-functionalized terpyridine molecule featuring a pyrrole heterocycle and a cyano group is described. This new compound was obtained via a KF/alumina-catalyzed Michael addition of 4 '-(pyrrol-2-yl)-2,2 ':6 ',2 ''-terpyridine into acrylonitrile. The mild reaction conditions leave the nitrile group unaltered. The title compound was fully characterized via NMR spectroscopy (H-1 and C-13) as well as via high resolution mass spectrometry and infrared spectroscopy.

引用

页数：4

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