Thermoresponsive block copolymers of increasing architecture complexity: a review on structure-property relationships

被引：37

作者：

Constantinou, Anna P. ^{[1
]}

Wang, Lezhi ^{[1
]}

Wang, Shaobai ^{[1
]}

Georgiou, Theoni K. ^{[1
]}

机构：

[1] Imperial Coll London, Dept Mat, South Kensington Campus, London SW7 2AZ, England

来源：

POLYMER CHEMISTRY | 2023年 / 14卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

ABA TRIBLOCK COPOLYMERS; PHASE-TRANSITION TEMPERATURE; POLY(ETHYLENE GLYCOL) B; SOL-GEL TRANSITION; AQUEOUS-SOLUTIONS; PENTABLOCK COPOLYMERS; MULTICOMPARTMENT HYDROGELS; THERMOREVERSIBLE GELATION; TRANSFECTION EFFICIENCY; ASSOCIATION PROPERTIES;

D O I：

10.1039/d2py01097f

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thermogels are an exciting class of stimuli responsive materials with many promising applications ranging from the medical field to additive manufacturing. This review focuses on the structure-property relationship of thermoresponsive block copolymers, with emphasis on the effect of architecture. Polymers based on Pluronic (R), N-isopropylacrylamide, oligo(ethylene glycol) (meth)acrylate units, and 2-oxazoline units, which are amongst the most studied thermoresponsive units, are discussed. The effect of the polymer's architecture is crucial for controlling the thermoresponsive properties, such as cloud point and gelation temperature.

引用

页码：223 / 247

页数：26

共 50 条

[41] STRUCTURE-PROPERTY RELATIONSHIPS IN FLEXIBLE SANDSTONE
DEVRIES, RC
JUGLE, DB
AMERICAN CERAMIC SOCIETY BULLETIN, 1966, 45 (04): : 369 - &
[42] STRUCTURE-PROPERTY RELATIONSHIPS IN AMORPHOUS POLYAMIDES
DOLDEN, JG
POLYMER, 1976, 17 (10) : 875 - 892
[43] STRUCTURE-PROPERTY RELATIONSHIPS IN CONDUCTIVE POLYMERS
BLOOR, D
MONKMAN, AP
STEVENS, GC
CHEUNG, KM
PUGH, S
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 187 : 231 - 239
[44] Structure-property relationships of conjugated polymers
Lawton, Samuel
Haddleton, David
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[45] Synthesis and Structure-Property Relationships of Cryogels
Okay, Oguz
Lozinsky, Vladimir I.
POLYMERIC CRYOGELS: MACROPOROUS GELS WITH REMARKABLE PROPERTIES, 2014, 263 : 103 - 157
[46] Structure-Property Relationships of Aromatic Polyesters
Sasanuma, Yuji
Suzukii, Nobuaki
KOBUNSHI RONBUNSHU, 2010, 67 (01) : 1 - 9
[47] Arylene-ethynylene/arylene-vinylene copolymers: Synthesis and structure-property relationships
Egbe, Daniel Ayuk Mbi
Carbonnier, Benjamin
Birckner, Eckhard
Grummt, Ulrich-Walter
PROGRESS IN POLYMER SCIENCE, 2009, 34 (10) : 1023 - 1067
[48] Structure-property relationships of blends of polycarbonate
Cheah, K
Cook, WD
POLYMER ENGINEERING AND SCIENCE, 2003, 43 (11): : 1727 - 1739
[49] IMPACT OF REGULARITY IN STRUCTURE-PROPERTY RELATIONSHIPS
MERCIER, C
SOBEL, Y
DUBOIS, JE
JOURNAL OF MATHEMATICAL CHEMISTRY, 1992, 9 (04) : 351 - 357
[50] STRUCTURE-PROPERTY RELATIONSHIPS IN POLYESTER FIBERS
SHAHIN, MM
POLYMER TESTING, 1995, 14 (03) : 243 - 251

← 1 2 3 4 5 →