Two-dimensional monoelement nanosheets produced from bulk crystals for potassium-ion storage

被引:2
|
作者
Luo, Wen [1 ]
Ru, Fei [1 ]
Yu, Dandan [1 ]
Liu, Hongjie [2 ]
Gao, Weiwei [2 ]
Song, Wenlong [2 ]
Chen, Da [1 ]
机构
[1] China Jiliang Univ, Coll Mat & Chem, Hangzhou 310018, Zhejiang, Peoples R China
[2] Tianneng Battery Grp Co Ltd, Changxing City 313100, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Energy storage and conversion; Potassium-ion batteries; Nanocrystalline materials; Tellurium; Two-dimensional materials; ANTIMONENE;
D O I
10.1016/j.cplett.2023.140824
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two-dimensional (2D) nanomaterials, particularly anisotropic monoelemental semiconductors, have attracted considerable attention for optoelectronic and electronic applications. Herein, a general substrate-free solution process is presented to prepare 2D non-layered selenium (Se)/tellurium (Te) and layered antimony (Sb) from bulk crystals. As a representative anode for K+ storage, the 2D Sb/mesoporous carbon (CMK-3) composite exhibits a high capacity up to 390.1 mAh/g at 50 mA g+1 and ultra-high retention of 98.9 % after 200 cycles, demonstrating that the reduced particle size and expanded interlayer distance effectively shorten the ionic diffusion pathway for fast kinetics.
引用
收藏
页数:5
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