Organometallic-Organic Hybrid Assemblies Featuring the Diantimony Complex [Cp2Mo2(CO)4(μ,η2-Sb2)], AgI Ions and N-Donor Molecules as Building Blocks

被引：3

作者：

Shelyganov, Pavel A. ^{[1
]}

Moussa, Mehdi Elsayed ^{[1
]}

Seidl, Michael ^{[1
,2
]}

Scheer, Manfred ^{[1
]}

机构：

[1] Univ Regensburg, Inst Inorgan Chem, D-93040 Regensburg, Germany

[2] Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, Ctr Chem & Biomed CCB, Innrain 80 82, A-6020 Innsbruck, Austria

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2023年 / 29卷 / 35期

关键词：

antimony; N-donor ligands; organometallic-organic hybrid assemblies; silver; supramolecular coordination complexes; COORDINATION POLYMERS; SILVER(I) COMPLEXES; BIPYRIDYL LINKERS; PI INTERACTIONS; LIGAND COMPLEX; PYRIDINE; DESIGN; PENTAPHOSPHAFERROCENE; ELEMENTS; BEHAVIOR;

D O I：

10.1002/chem.202300610

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of the organometallic ligand complex [Cp2Mo2(CO)(4)(mu,eta(2)-Sb-2)] (C) with Ag[TEF] ([TEF](-)=[Al{OC(CF3)(3)}(4)](-)) in the presence of a number of di- or polytopic N-donor molecules (1,6,7,12-tetraazaperylene (L1), 2,2'-bipyrimidine (L2), 4,4'-bipyridine (L3), trans-1,2-di(4-pyridyl)ethylene (L4) and 1,3-di(4-pyridyl)propane (L5)), were studied. Depending on the reaction stoichiometry and choice of linker, these reactions lead to the selective formation of dimeric or tetrameric supramolecular coordination complexes as well as 1D and 2D coordination polymers (CPs). The presented compounds are unique examples of supramolecular complexes incorporating both organometallic Sb-donor and organic N-donor molecules as ligands to stabilize metal ions. Moreover, one of the formed compounds, the CP [Ag-4(eta(2 : 1)-C)(4)(L4)(4)](n)[TEF](4n), represents an exceptional 1D polymer incorporating both N- and Sb-donor ligands as connectors for metal ions.

引用

页数：8

共 45 条

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