Thermo physical properties and IR spectral studies of some binary liquid mixtures and correlation with the Jouyban-Acree model

被引：0
|
作者：
Chinni, M. [1 ]
Aravind, S. [2 ]
Ramachandran, D. [1 ]
Sankar, M. Gowri [3 ]
Subbarao, M. [1 ,4 ]
机构：
[1] Acharya Nagarjuna Univ, Univ Coll Sci, Dept Chem, Guntur, India
[2] Osmania Univ, Hyderabad, Telangana, India
[3] JKC Coll, Dept Chem, Guntur, India
[4] Acharya Nagarjuna Univ, Univ Coll Sci, Dept Chem, Guntur 522510, Andhra Prades, India
来源：
PHYSICS AND CHEMISTRY OF LIQUIDS | 2024年 / 62卷 / 06期
关键词：
Propargyl alcohol; different functional groups; Jouyban-Acree model; FTIR spectra; THERMODYNAMIC PROPERTIES; BENZYL ALCOHOL; DENSITIES; VISCOSITY; TEMPERATURE; BENZENE; CHAIN; SOUND;
D O I：
10.1080/00319104.2024.2333955
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Excess molar volume, excess isentropic compressibility, deviation in viscosity and excess Gibbs free energy for activation of viscous flow for binary mixtures of propargyl alcohol (J) with benzyl aldehyde (J1), benzylamine (J2) and benzyl alcohol (J3) components with selected compositions were determined from the measured values of densities (rho), viscosities (eta), and speeds of sound (u) of pure components and their mixtures from 303.15 K to 313.15 K. The effect of various functional groups on the excess properties has been discussed in terms of attractive forces between the components. The results of the Jouyban-Acree model are discussed in terms of the mean relative deviation and individual relative between the calculated and experimental densities, speed of sound, and viscosities as an accuracy criterion.FTIR studies have also been added to confirm the experimental findings of the investigated mixtures
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收藏
页码：583 / 602
页数：20
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