In-pile tritium release behavior and the post-irradiation experiments of Li4SiO4 fabricated by melting process

Understanding the tritium release and retention behavior of candidate tritium breeder materials is crucial for breeder blanket design. Recently, a melt spraying process was developed to prepare Li4SiO4 pebbles, which were subsequently subjected to the in-pile tritium production and extraction platform in China Mianyang Research Reactor (CMRR) to investigate their in-situ tritium release behavior and irradiation performance. The results demonstrate that HT is the main tritium release form, and adding hydrogen to the purge gas reduces tritium retention while increasing the HT percent in the purge gas. Post-irradiation experiments reveal that the irradiated pebbles darken in color and their grains swell, but the mechanical properties remain largely unchanged. It is concluded that the tritium residence time of Li4SiO4 made by melt spraying method at 467 degrees C is approximately 23.34 h. High-density Li4SiO4 pebbles exhibit tritium release at relatively low temperatures (< 600 degrees C) that is mainly controlled by bulk diffusion. The diffusion coefficient at 525 degrees C and 550 degrees C is 1.19 x 10(-11) cm(2)/s and 5.34 x 10(-11) cm(2)/s, respectively, with corresponding tritium residence times of 21.3 hours and 4.7 hours.