Efficient and stable neutral zinc-air batteries by three-dimensional ordered macroporous N-doped carbon frameworks loading NiN4 active sites

被引：3
|
作者：
Cai, Zihe [1 ]
Li, Menglei [1 ]
Hu, Xiaobin [2 ]
Zheng, Lirong [3 ]
机构：
[1] China Huaneng Grp Clean Enery Res Inst, Beijing 102209, Peoples R China
[2] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
[3] Chinese Acad Sci, Beijing Synchrotron Radiat Facil BSRF, Inst High Energy Phys, Beijing 100049, Beijing, Peoples R China
来源：
MATERIALS LETTERS | 2023年 / 331卷
基金：
中国国家自然科学基金;
关键词：
Oxygen reduction reaction; Oxygen evolution reaction; Neutral zinc-air batteries; 3DOM; NiN4 active sites; ELECTROLYTE; CATALYSTS;
D O I：
10.1016/j.matlet.2022.133462
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Neutral zinc-air batteries prevent the carbon based catalysts from being oxidized during cycling, which show excellent potential for long-term energy storage. Three-dimensional ordered macroporous nitrogen doped carbon frameworks with NiN4 (3DOM Ni-N-C) were constructed by in situ reaction of Ni nanoparticles and dicyandiamide. The 3DOM Ni-N-C bifunctional catalysts exhibit comparable oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) efficiency and stablity. The 3D interconnected structure of 3DOM Ni-N-C provides sufficient channel for mass transfer, resulting in high power density (35 mW cm(-2)) and long cycle life (580 cycles) of neutral zinc-air batteries. Meanwhile the failure mechanism in neutral electrolyte was discussed.
引用
收藏
页数：3
相关论文
共 50 条
  • [41] N-doped hollow carbon tubes derived N-HCTs@NiCo2O4 as bifunctional oxygen electrocatalysts for rechargeable Zinc-air batteries
    Fu, Dongju
    Zhu, ZiYue
    Chen, Jianjun
    Ye, Liqiang
    Song, XinRui
    Zeng, XieRong
    Journal of Electroanalytical Chemistry, 2021, 902
  • [42] Shrimp-shell derived carbon nanodots as precursors to fabricate Fe,N-doped porous graphitic carbon electrocatalysts for efficient oxygen reduction in zinc-air batteries
    Zhang, Xian
    Liu, Rongrong
    Zang, Yipeng
    Liu, Guoqiang
    Liu, Shengwen
    Wang, Guozhong
    Zhang, Yunxia
    Zhang, Haimin
    Zhao, Huijun
    INORGANIC CHEMISTRY FRONTIERS, 2016, 3 (07): : 910 - 918
  • [43] Single-atom Co-N 4 catalytic sites anchored on N-doped ordered mesoporous carbon for excellent Zn-air batteries
    Li, Na
    Li, Le
    Xia, Jiawei
    Arif, Muhammad
    Zhou, Shilong
    Yin, Fengxiang
    He, Guangyu
    Chen, Haiqun
    JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2023, 139 : 224 - 231
  • [44] FeCo Nanoparticles Encapsulated in N-Doped Carbon Nanotubes Coupled with Layered Double (Co, Fe) Hydroxide as an Efficient Bifunctional Catalyst for Rechargeable Zinc-Air Batteries
    Zhang, Tongrui
    Bian, Juanjuan
    Zhu, Yuanqin
    Sun, Chunwen
    SMALL, 2021, 17 (44)
  • [45] Cu/Co/CoS2 embedded in S,N-doped carbon as highly efficient oxygen reduction and evolution electrocatalyst for rechargeable zinc-air batteries
    Zhao, Yiwei
    Sun, Qiming
    Liu, Xianchun
    Li, Dehua
    Xing, Shuangxi
    INORGANIC CHEMISTRY FRONTIERS, 2022, 9 (12) : 2917 - 2927
  • [46] Fe0.64Ni0.36@Fe3NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability
    Pu, Chen
    Deng, Daijie
    Li, Henan
    Xu, Li
    ACTA PHYSICO-CHIMICA SINICA, 2024, 40 (02)
  • [47] Well entrapped platinum-iron nanoparticles on three-dimensional nitrogen-doped ordered mesoporous carbon as highly efficient and durable catalyst for oxygen reduction and zinc-air battery
    Sun, Rui-Min
    Wu, Run-Ze
    Li, Xin-Sheng
    Feng, Jiu-Ju
    Zhang, Lu
    Wang, Ai-Jun
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2022, 621 : 275 - 284
  • [48] Doping-engineered bifunctional oxygen electrocatalyst with Se/Fe-doped Co3O4/N-doped carbon nanosheets as highly efficient rechargeable zinc-air batteries
    Zhao, Hong
    Yao, Huixue
    Wang, Shuting
    Cao, Yali
    Lu, Zhenjiang
    Xie, Jing
    Hu, Jindou
    Hao, Aize
    Journal of Colloid and Interface Science, 2022, 626 : 475 - 485
  • [49] Doping-engineered bifunctional oxygen electrocatalyst with Se/Fe-doped Co3O4/N-doped carbon nanosheets as highly efficient rechargeable zinc-air batteries
    Zhao, Hong
    Yao, Huixue
    Wang, Shuting
    Cao, Yali
    Lu, Zhenjiang
    Xie, Jing
    Hu, Jindou
    Hao, Aize
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2022, 626 : 475 - 485
  • [50] Deriving paired Fe sites on N-doped carbon from Fe(III)-tetrapyridinylporphyrin-modified ZIF-8: robust electrocatalysts for air electrodes in zinc-air batteries
    Yang, Guiyuan
    Hu, Fangyuan
    Cui, Li-Li
    Fan, Meihong
    Ge, Xin
    He, Xingquan
    Zhang, Wei
    Asefa, Tewodros
    INORGANIC CHEMISTRY FRONTIERS, 2024, 11 (06) : 1764 - 1774
12345