Metal organic frameworks derived NiSe2 microspheres wrapped with graphene as a high-performance cathode for rechargeable magnesium batteries

被引：3
|
作者：
Hu, Changchun [1 ,2 ]
Wang, Chengzhe [1 ,2 ]
Xia, Yaping [1 ,2 ]
Xu, Fei [3 ]
Li, Ting [1 ,2 ]
机构：
[1] South Cent Minzu Univ, Key Lab Catalysis & Energy Mat Chem, Minist Educ, Wuhan 430074, Peoples R China
[2] South Cent Minzu Univ, Hubei R&D Ctr Hyperbranched Polymers Synthesis& Ap, Hubei Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China
[3] Wuhan Univ, Sch Power & Mech Engn, Wuhan 430072, Peoples R China
来源：
MATERIALS LETTERS | 2023年 / 341卷
基金：
中国国家自然科学基金;
关键词：
Energy storage and conversion; Nanocomposites; Composite materials;
D O I：
10.1016/j.matlet.2023.134241
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Rechargeable magnesium batteries (RMBs) are suitable for large-scale energy storage, but the cathode materials are deficient. Herein, NiSe2 microspheres derived from Ni-metal organic frameworks (Ni-MOFs) and wrapped with reduced graphene oxide (NiSe2/rGO) are fabricated and used as RMB cathodes. The NiSe2 microspheres are composed of tiny nanoparticles and interweaved with conductive graphene network. The NiSe2/rGO cathode exhibits a capacity of 215.5 mAh g(-1) at 50 mA g(-1), a good rate capability of 66.8 mAh g(-1) at 2.0 A g(-1) and a stable cycling for 300 cycles. Further kinetic investigation indicates the graphene improves the activity of the tiny NiSe2 nanoparticles, enhancing the interphase charge transfer and the magnesium storage performance.
引用
收藏
页数：5
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