Siloxane-containing phosphine (oxide) ligands for enhanced catalytic activity of cobalt complexes for hydrosilylation reactions

被引：2

作者：

Liu, Peng ^{[1
]}

Peng, Jiajian ^{[1
]}

Bai, Ying ^{[1
]}

Li, Jiayun ^{[1
]}

机构：

[1] Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Key Lab Organosilicon Mat Technol Zhejiang Prov, Coll Mat Chem & Chem Engn,Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2024年 / 22卷 / 16期

关键词：

ENANTIOSELECTIVE HYDROSILYLATION; REGIODIVERGENT HYDROSILYLATION; ALKENE HYDROSILYLATION; IRON; 1,2-HYDROSILYLATION; HYDROGENATION; SILANES; OLEFINS;

D O I：

10.1039/d4ob00333k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of siloxane-containing phosphine (oxide) ligands have been designed and synthesized. These phosphine (oxide) ligands contain silicon atoms, which can impart better solubility in the relevant media, thereby improving certain catalytic performances. The hydrosilylation of olefins catalyzed by these metal phosphine (oxide) complexes has been conducted under mild reaction conditions. A series of siloxane-containing phosphine (oxide) ligands have been designed and synthesized.

引用

页码：3304 / 3313

页数：10

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