Electronic structure modification of SnO2 to accelerate CO2 reduction towards formate

被引：1
|
作者：
Li, Lulu [1 ,2 ]
Wu, Shican [1 ,2 ]
Cheng, Dongfang [3 ]
Zhao, Zhi-Jian [1 ,2 ,4 ]
Gong, Jinlong [1 ,2 ,5 ,6 ,7 ]
机构：
[1] Tianjin Univ, Sch Chem Engn & Technol, Key Lab Green Chem Technol, Minist Educ, Tianjin 300072, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
[3] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA 90095 USA
[4] Joint Sch Natl Univ Singapore, Singapore, Singapore
[5] Tianjin Univ, Int Campus Tianjin Univ, Fuzhou 350207, Peoples R China
[6] Haihe Lab Sustainable Chem Transformat, Tianjin 300192, Peoples R China
[7] Tianjin Univ, Natl Ind Educ Platform Energy Storage, 135 Yaguan Rd, Tianjin 300350, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 29期
基金：
中国国家自然科学基金; 国家重点研发计划;
关键词：
Catalyst activity;
D O I：
10.1039/d3cc06337b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A systematic theoretical study probing the catalytic potential of metal-doped SnO2(110) was conducted. The incorporation of metals such as Zr, Ti, W, V, Hf, and Ge is shown to drive electron transfer to Sn. The increased charge of Sn is injected into anti-bonding orbitals, finely tuning the catalytic activity and reducing the overpotential to -0.34 V. AIMD simulations show the stability of the modified structures. This work sheds light on the rational design of low-cost metal oxides with a high catalytic performance for CO2ER to formate.
引用
收藏
页码：3922 / 3925
页数：4
相关论文
共 50 条
  • [41] Stabilizing Oxidation State of SnO2 for Highly Selective CO2 Electroreduction to Formate at Large Current Densities
    Jiang, Yunling
    Shan, Jieqiong
    Wang, Pengtang
    Huang, Linsen
    Zheng, Yao
    Qiao, Shi-Zhang
    ACS CATALYSIS, 2023, 13 (05) : 3101 - 3108
  • [42] Defect engineered SnO2 nanoparticles enable strong CO2 chemisorption toward efficient electroconversion to formate
    Ning, Baoxing
    Liu, Miaomiao
    Hu, Yanjie
    Jiang, Hao
    Li, Chunzhong
    DALTON TRANSACTIONS, 2022, 51 (09) : 3512 - 3519
  • [43] Modulating Electronic Structure of Amorphous Indium Oxide for Efficient Formate Synthesis Towards CO2 Electroreduction
    Gao, Yuanxiang
    Yang, Zhengwu
    Zhao, Jiankang
    Kong, Xiangdong
    Geng, Zhigang
    CHEMISTRY-AN ASIAN JOURNAL, 2025, 20 (03)
  • [44] Deciphering Structure-Activity Relationship Towards CO2 Electroreduction over SnO2 by A Standard Research Paradigm
    Guo, Zhongyuan
    Yu, Yihong
    Li, Congcong
    dos Santos, Egon Campos
    Wang, Tianyi
    Li, Huihui
    Xu, Jiang
    Liu, Chuangwei
    Li, Hao
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (12)
  • [45] Modification of the CuO electronic structure for enhanced selective electrochemical CO2 reduction to ethylene
    Wu, Xin
    Tong, Zhuang
    Liu, Yunliang
    Li, Yaxi
    Cheng, Yuanyuan
    Yu, Jingwen
    Cao, Peng
    Zhuang, Chunqiang
    Shi, Qiuzhong
    Liu, Naiyun
    Liu, Xiang
    Liang, Hongyu
    Li, Haitao
    NANO RESEARCH, 2024, 17 (08) : 7194 - 7202
  • [46] Surface structure-dependent electrocatalytic reduction of CO2 to C1 products on SnO2 catalysts
    Fang, Minling
    Zheng, Zhiping
    Chen, Jiayu
    Chen, Qian
    Liu, Deyu
    Xu, Binbin
    Wu, Jianyang
    Kuang, Qin
    Xie, Zhaoxiong
    SUSTAINABLE ENERGY & FUELS, 2020, 4 (02) : 600 - 606
  • [47] Molecular catalysts for the reduction of CO2 to CO or formate
    Appel, Aaron M.
    Linehan, John C.
    Boro, Brian J.
    Galan, Brandon R.
    Jeletic, Matthew S.
    Peterson, Sonja M.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
  • [48] Interaction between InP and SnO2 on TiO2 nanotubes for photoelectrocatalytic reduction of CO2
    Zheng, Jingui
    Hu, Fengyun
    Han, Ershuan
    Pan, Zhengbin
    Zhang, Shuai
    Li, Ya
    Qin, Peiguang
    Wang, Hui
    Li, Peiqiang
    Yin, Hongzong
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2019, 575 : 329 - 335
  • [49] Band alignment in Zn2SnO4/SnO2 heterostructure enabling efficient CO2 electrochemical reduction
    Wang, Ke
    Liu, Dongyu
    Deng, Peilin
    Liu, Limin
    Lu, Shiyao
    Sun, Zongjie
    Ma, Yarning
    Wang, Yuankun
    Li, Mingtao
    Xia, Bao Yu
    Xiao, Chunhui
    Ding, Shujiang
    NANO ENERGY, 2019, 64
  • [50] Electrochemical CO2 reduction over nitrogen-doped SnO2 crystal surfaces
    Zhang, Yuefeng
    Liu, Jianjun
    Wei, Zengxi
    Liu, Quanhui
    Wang, Caiyun
    Ma, Jianmin
    JOURNAL OF ENERGY CHEMISTRY, 2019, 33 : 22 - 30
12345