Advance of Dehydrogenation and Transfer Hydrogenation of Ammonia-Borane Catalyzed by Homogeneous Cobalt Complexes

被引：3
|
作者：
Liu Shuang [1 ,2 ]
Zou Lianghua [1 ]
Wang Xiaoming [2 ]
机构：
[1] Jiangnan Univ, Sch Life Sci & Hlth Engn, Wuxi 214122, Jiangsu, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 43卷 / 05期
关键词：
ammonia borane; homogeneous catalysis; cobalt complex; dehydrogenation; transfer hydrogenation; DIMETHYLAMINE-BORANE; CHEMISTRY; MECHANISM; ALKYNES; DEHYDROPOLYMERISATION; SEMIHYDROGENATION; HYDROSILYLATION; ISOMERIZATION; AMINOBORANE; SILANES;
D O I：
10.6023/cjoc202302020
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
As an ideal chemical hydrogen storage material, efficient dehydrogenation and transfer hydrogenation of ammonia borane has attracted increasing attention. Due to the advantages of cheap and easy availability and biocompatibility of earth-abundant metals, the development of homogeneous catalytic dehydrogenation and related transformation of ammonia borane with earth-abundant metals is a significant research topic in this field. Herein, the development of dehydrogenation and transfer hydrogenation of ammonia borane catalyzed by homogeneous cobalt complexes is reviewed.
引用
收藏
页码：1713 / 1725
页数：13
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