Green Hydrogenation of C=C, C=O, and C=N Bonds in Water by Palladium-Tin Bimetallic Nanoparticles

被引：2

作者：

Mukhi, Priyabrata ^{[1
]}

Nayak, Mukesh Kumar ^{[1
]}

Mohanty, Anuradha ^{[1
]}

Roy, Sujit ^{[1
]}

机构：

[1] Indian Inst Technol Bhubaneswar, Sch Basic Sci, Organometall & Catalysis Lab, Khurja 752050, Odisha, India

来源：

CHEMISTRYSELECT | 2023年 / 8卷 / 42期

关键词：

alpha; beta-unsaturated compounds; Bimetallic Nanoparticle; Hydrogenation; Palladium; Tin; CHEMOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; CATALYTIC-HYDROGENATION; PD; TEMPERATURE; REDUCTION; GOLD; SIZE; CINNAMALDEHYDE; 1,3-BUTADIENE;

D O I：

10.1002/slct.202302508

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of various functional groups under atmospheric H2 by Pd-Sn nanoparticles in water is reported. A broad set of C-C, C-O, and C-N multiple bonds were reduced using a catalyst loading of 0.56 mol % to give rise to a high yield of products up to 99 % and good tolerance with various substrates. Additionally, the bimetallic Pd-Sn system successively hydrogenated the olefinic double bond of alpha,beta-unsaturated carbonyl compounds with selectivity up to 99 % demonstrating further its chemoselectivity. The catalyst is recyclable for up to five cycles with alpha-methyl styrene as the substrate. However, with functionalized alkenes such as acrylic acid, the recyclability was poor.

引用

页数：10

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