Mercury bioaccumulation and speciation in coastal invertebrates: Implications for trophic magnification in a marine food web

Studies on mercury bioaccumulation and biomagnification in coastal invertebrates in eastern Canada are limited, but these data are necessary to determine risk of mercury exposure effects in upper trophic level organisms. We quantified methylmercury (MeHg), total mercury (THg), and stable isotopes of delta 13C and delta 15N in 14 species of invertebrates in the Minas Basin. The overall mean concentration of MeHg (12.78 +/- 11.23 ng/g dw) was approximately 10 times below the Canadian guideline for the protection of wildlife consumers like fish and birds of 157.20 ng/g dry weight (dw). Invertebrates at higher trophic positions (delta 15N) had greater THg and particu-larly MeHg. The Trophic Magnification Factors (TMF) for MeHg and THg (1.59 and 1.21 respectively) were similar to others reported in studies of food webs containing higher trophic level organisms.