Denitrative Mizoroki-Heck reaction of unactivated alkenes

被引：6
|
作者：
Zhang, Fei [1 ]
Wang, Fei [1 ]
Zhao, Yao [1 ]
Chen, Rizhi [2 ]
Wu, Xiaojin [1 ]
机构：
[1] Nanjing Tech Univ, Inst Adv Synth, Sch Chem & Mol Engn, Nanjing 211816, Peoples R China
[2] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 09期
基金：
中国国家自然科学基金;
关键词：
ARYLBORONIC ACIDS; COUPLING REACTION; NITROARENES; AMINATION; CHLORIDES; CATALYST; SUZUKI;
D O I：
10.1039/d3qo00132f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A general palladium-catalyzed denitrative Mizoroki-Heck reaction of unactivated alkenes was developed. Most topical classes of nitroarenes efficiently react with various unactivated alkenes with high E/Z selectivity. A gram-scale reaction, chemoselective dual Heck transformation and modification of complex molecules have further demonstrated that the denitrative reaction of unactivated alkenes is a powerful complementary strategy to the classical Mizoroki-Heck reaction.
引用
收藏
页码：2193 / 2197
页数：5
相关论文
共 50 条
  • [41] Mizoroki-Heck reaction over palladium nanoparticles supported on WO3
    Amini, Mojtaba
    Heydarloo, Dina Bahrami
    Rahimi, Mohammad
    Kim, Min Gyu
    Gautam, Sanjeev
    Chae, Keun Hwa
    MATERIALS RESEARCH BULLETIN, 2016, 83 : 179 - 185
  • [42] Cyrene: a bio-based solvent for the Mizoroki-Heck reaction of aryl iodides
    Stini, Naya A. A.
    Gkizis, Petros L. L.
    Kokotos, Christoforos G. G.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2023, 21 (02) : 351 - 358
  • [43] Synthesis of the eight-membered carbocycle of brachialactone by intramolecular Mizoroki-Heck reaction
    Hirata, Yushi
    Nakazaki, Atsuo
    Nishikawa, Toshio
    TETRAHEDRON LETTERS, 2022, 90
  • [44] Preparation of polymer anchored Pd-catalysts: Application in Mizoroki-Heck Reaction
    Patel, S. A.
    Patel, K. N.
    Sinha, S.
    Kamath, B. V.
    Bedekar, A. V.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 332 (1-2) : 70 - 75
  • [45] Oxidative Mizoroki-Heck reaction of unprotected cinnamylamines at ambient temperature under air
    Farinde, Olutayo N.
    Satheesh, Vanaparthi
    Shrestha, Kendra K.
    Rhinehalt, Carmen R.
    Landge, Vinod G.
    Young, Michael C.
    ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (16) : 3982 - 3988
  • [46] MnBr2 catalyzed regiospecific oxidative Mizoroki-Heck type reaction
    Xiang Chen
    Zhihong Zhu
    Shanshan Liu
    Yi-Hung Chen
    Xiao Shen
    Chinese Chemical Letters, 2022, 33 (05) : 2391 - 2396
  • [47] Supported Liquid Phase Catalyst coating in micro flow Mizoroki-Heck reaction
    Stouten, S. C.
    Noel, T.
    Wang, Q.
    Hessel, V.
    CHEMICAL ENGINEERING JOURNAL, 2015, 279 : 143 - 148
  • [48] Pd-NHC Catalyzed Conjugate Addition versus the Mizoroki-Heck Reaction
    Gottumukkala, Aditya L.
    de Vries, Johannes G.
    Minnaard, Adriaan J.
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (11) : 3091 - 3095
  • [49] Iron-Catalyzed Mizoroki-Heck Cross-Coupling Reaction with Styrenes
    Loska, Rafal
    Volla, Chandra M. Rao
    Vogel, Pierre
    ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (18) : 2859 - 2864
  • [50] Supported Liquid Phase Catalyst coating in micro flow Mizoroki-Heck reaction
    Hessel, V. (v.hessel@tue.nl), 1600, Elsevier B.V., Netherlands (279):
12345