Palladium-Catalyzed Aminocarbonylation of Aryl Halides

被引：12

作者：

Afsina, Cheriya Mukkolakkal Abdulla ^{[1
]}

Philip, Rose Mary ^{[1
]}

Saranya, Padinjare Veetil ^{[1
]}

Anilkumar, Gopinathan ^{[1
]}

机构：

[1] Mahatma Gandhi Univ, Sch Chem Sci, Priyadarsini Hills PO, Kottayam 686560, Kerala, India

来源：

CURRENT ORGANIC SYNTHESIS | 2023年 / 20卷 / 03期

关键词：

Aminocarbonylation; aryl halides; amines; CO; palladium catalyst; amide synthesis; MONOXIDE-FREE AMINOCARBONYLATION; EX-SITU GENERATION; CARBON-MONOXIDE; PRIMARY AMIDES; ATMOSPHERIC-PRESSURE; CARBOXYLIC-ACIDS; AROMATIC AMIDES; TERTIARY-AMINES; EFFICIENT; CARBONYLATION;

D O I：

10.2174/1570179419666220430150122

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed organic reactions are ubiquitous due to their high efficiency in coupling reactions and have wide applications in synthetic chemistry. Their widespread use in organic synthesis has been attributed to moderate conditions associated with reactions and tolerance to different types of functional groups. Palladium-catalysts are extensively used in aminocarbonylation of aryl halides for the synthesis of amides and have found a wide variety of applications in pharmaceuticals, agrochemicals, petrochemicals, materials, polymers, etc. In this review, we summarize the recent advances in the synthesis of amides via palladium-catalyzed aminocarbonylation of aryl halides, and cover literature from 2010 to 2021.

引用

页码：308 / 331

页数：24

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