Influence of oxalic acid on the corrosion behavior of AZ91D magnesium alloy in deionized water

被引：6
|
作者：
Liu, Sisi [1 ]
Huang, Hualiang [1 ]
Huang, Gangliang [2 ]
Qu, June [3 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Key Lab Green Chem Proc, Key Lab Novel Reactor & Green Chem Technol Hubei P, Wuhan 430074, Peoples R China
[2] Chongqing Normal Univ, Key Lab Carbohydrate Sci & Engn, Chongqing 401331, Peoples R China
[3] Hubei Univ, Key Lab Green Preparat & Applicat Funct Mat, Minist Educ, Wuhan 430062, Peoples R China
来源：
VACUUM | 2023年 / 215卷
基金：
中国国家自然科学基金;
关键词：
Magnesium alloy; Oxalic acid; Corrosion; Hydrogen evolution; ETHYLENE-GLYCOL; SURFACE-CHEMISTRY; IMPEDANCE; AZ31; MECHANISM; AMBIENT; XPS;
D O I：
10.1016/j.vacuum.2023.112351
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Due to its light weight, Mg alloy can be applied to automotive engines and cooling systems to reduce vehicle weight, energy consumption and exhaust pollution. However, ethylene glycol-type coolants can be oxidized into oxalic acid, glyoxylic acid and other substances at high temperature, which can cause the damage of Mg alloy. In this paper, electrochemical methods, hydrogen evolution and surface analysis methods were used to study the influence of oxalic acid on the corrosion behavior of AZ91D magnesium alloy in deionized water. The results indicated that the oxalic acid accelerated the corrosion of Mg alloy, and its corrosion rate increased with the concentration of oxalic acid. However, interestingly, the corrosion rate of Mg alloy in oxalic acid solution slowed as the immersed time lengthened, which could be related to the accumulation of corrosion products and the consumption of hydrogen ions. The main corrosion product of the corrosion of Mg alloy in oxalic acid solution was composed of magnesium oxalate.
引用
收藏
页数：11
相关论文
共 50 条
  • [31] Corrosion behavior of corrosion resistant film on az91d magnesium alloys
    Lai, Yong-Lai
    Li, Wang
    Jin, Hua-Lan
    Peng, Wen-Yi
    Guo, Hong-Min
    Yang, Xiang-Jie
    Surface Technology, 2020, 49 (12): : 235 - 243
  • [32] Fabrication and corrosion behavior of TiO2 nanotubes on AZ91D magnesium alloy
    Li, Jianfang
    He, Xiaojing
    Hang, Ruiqiang
    Huang, Xiaobo
    Zhang, Xiangyu
    Tang, Bin
    CERAMICS INTERNATIONAL, 2017, 43 (16) : 13683 - 13688
  • [33] Corrosion Behavior of AZ91D Magnesium Alloy in Atmosphere Containing SO2
    Lin Cui
    Liang Jianneng
    RARE METAL MATERIALS AND ENGINEERING, 2011, 40 (03) : 499 - 502
  • [34] Galvanic corrosion behavior of die cast AZ91D magnesium alloy in chloride solution
    Tong, ZS
    Zhang, W
    Li, JQ
    Gao, J
    He, JQ
    Zhou, J
    JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING, 2004, 11 (02): : 127 - 132
  • [35] Corrosion behavior of magnesium alloys AZ91D in NaCl solution
    Bai L.-Q.
    Shu K.-Y.
    Li D.
    Hangkong Cailiao Xuebao/Journal of Aeronautical Materials, 2010, 30 (01): : 62 - 66
  • [36] Tribological behavior of AZ91D magnesium alloy at elevated temperatures
    Zafari, A.
    Ghasemi, H. M.
    Mahmudi, R.
    WEAR, 2012, 292 : 33 - 40
  • [37] Fatigue crack propagation behavior of AZ91D magnesium alloy
    Jung, HC
    Yim, CD
    Park, WW
    Lee, CS
    Shin, KS
    MAGNESIUM ALLOYS 2003, PTS 1 AND 2, 2003, 419-4 : 75 - 80
  • [38] Investigation of the compressive creep behavior of AZ91D magnesium alloy
    Guo, Jin-hua
    Chen, Li-qing
    Yong-bo Xu
    Fa-zeng Lian
    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 443 (1-2): : 66 - 70
  • [39] Electrochemical corrosion behavior of AZ91D alloy in ethylene glycol
    Fekry, A. M.
    Fatayerji, M. Z.
    ELECTROCHIMICA ACTA, 2009, 54 (26) : 6522 - 6528
  • [40] Corrosion behaviour of laser surface melted magnesium alloy AZ91D
    Taltavull, C.
    Torres, B.
    Lopez, A. J.
    Rodrigo, P.
    Otero, E.
    Atrens, A.
    Rams, J.
    MATERIALS & DESIGN, 2014, 57 : 40 - 50
12345