Enantioselective disruption of cellulose nanocrystal self-assembly into chiral nematic phases in <sc>d</sc>-alanine solutions

被引：1

作者：

Attia, David ^{[1
]}

Mendelson, Orit ^{[1
,2
]}

Levi-Kalisman, Yael ^{[3
,4
]}

Bitton, Ronit ^{[1
,5
]}

Yerushalmi-Rozen, Rachel ^{[1
,5
]}

机构：

[1] Ben Gurion Univ Negev, Dept Chem Engn, IL-84105 Beer Sheva, Israel

[2] Nucl Res Ctr Negev, Dept Chem, IL-84190 Beer Sheva, Israel

[3] Hebrew Univ Jerusalem, Ctr Nanosci & Nanotechnol, IL-91904 Jerusalem, Israel

[4] Hebrew Univ Jerusalem, Inst Life Sci, IL-91904 Jerusalem, Israel

[5] Ben Gurion Univ Negev, Ilse Katz Inst Nanosci & Technol, IL-84105 Beer Sheva, Israel

来源：

NANOSCALE | 2023年 / 15卷 / 42期

关键词：

X-RAY; NANOCELLULOSE; FILMS; SUSPENSIONS; NANOFIBRILS; SCATTERING;

D O I：

10.1039/d3nr03077f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chiral environment of enantiomerically pure d-alanine solutions is observed to disrupt and modify the entropy-driven assembly of cellulose nanocrystals (CNCs) into a chiral nematic mesophase. The effect is specific to d-alanine and cannot be attributed to the adsorption of alanine molecules (neither d- nor l-alanine) onto the CNC particles.

引用

页码：16890 / 16895

页数：6

共 13 条

[11] Entropy-driven self-assembly of chiral nematic liquid crystalline phases of AgNR@Cu2O hyper branched coaxial nanorods and thickness-dependent handedness transition
Guiqing Cheng
Yu Wang
Kun Liu
Jihong Yu
Nano Research, 2018, 11 : 1018 - 1028
[12] Modeling of Self-Organization Processes in Crystal-Forming Systems: Symmetry and Topological Codes of Cluster Self-Assembly of a 2D Layered Icosahedral Structure of Sc18B238 (Pbam, oP514)
Shevchenko, V. Ya.
Blatov, V. A.
Ilyushin, G. D.
GLASS PHYSICS AND CHEMISTRY, 2016, 42 (03) : 221 - 229
[13] Modeling of self-organization processes in crystal-forming systems: Symmetry and topological codes of cluster self-assembly of a 2D layered icosahedral structure of Sc18B238 (Pbam, oP514)
V. Ya. Shevchenko
V. A. Blatov
G. D. Ilyushin
Glass Physics and Chemistry, 2016, 42 : 221 - 229

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