Synthesis,Structure and Thermal Property of a Cobalt Supramolecular Complex Containing N-[(4-Carboxyphenyl)-sulfonyl]glycine

被引：1
|
作者：
王永伟 [1 ]
王利亚 [2 ]
机构：
[1] Department of Chemistry and Chemical Engineering,Ankang University
[2] College of Chemistry and Chemical Engineering,Luoyang Normal University
来源：
结构化学 | 2010年 / 29卷 / 10期
基金：
中国国家自然科学基金;
关键词：
N-[(4-carboxyphenyl)-sulfonyl]glycine; supramolecular complex; thermal property;
D O I：
10.14102/j.cnki.0254-5861.2010.10.019
中图分类号：
O621.2 [有机化合物性质];
学科分类号：
摘要：
Utilizing N-[(4-carboxyphenyl)-sulfonyl]glycine (abbreviated as cbsglyH3),a new cobalt complex [Co(cbsglyH)(bipy)2]3H2O (bipy = 2,2’-bipyridine) has been synthesized under mild conditions and characterized by IR,elemental analysis,thermogravimetric analysis and X-ray diffraction analysis. It crystallizes in the monoclinic system,space group C2/c with a = 34.978(3),b = 12.0437(11),c = 20.0041(19) ,β = 122.2990(10)°,V = 7123.0(11) 3,Z = 8,C29H28CoN5O9S,Mr = 681.55,μ = 0.593 mm-1,Dc = 1.271 Kg/m3,F(000) = 2816,the final R = 0.0434 and wR = 0.1351. The title complex is a monomeric compound which is further assembled by intermolecular hydrogen bonds into a 3-D supramolecular network. Thermogravimetric analysis illustrates that this complex begins decomposing at 100 ℃ and decompounding completely at 560 ℃.
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收藏
页码：1579 / 1583
页数：5
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