Fe-modified HZSM-5 catalysts for ethanol conversion into light olefins

被引：0
|
作者：
Jiangyin Lu
机构：
来源：
Journal of Natural Gas Chemistry | 2011年 / 04期
基金：
中国国家自然科学基金;
关键词：
bio-ethanol; light olefins; HZSM-5; Fe modification;
D O I：
暂无
中图分类号：
TQ203.2 [催化过程];
学科分类号：
081705 ;
摘要：
A series of Fe/HZSM-5 catalysts with different iron loadings were prepared by impregnation method.Characterization was performed by N2 adsorption-desorption,X-ray diffraction(XRD),NH3 temperature-programmed desorption(NH3-TPD),temperature-programmed reduction (TPR),temperature-programmed oxidation(TPO)and thermogravimetry(TG)analysis.Iron content in the synthesized samples varied from 1.1 wt%to 20 wt%.The obtained samples have been used for ethanol conversion into light olefins.It was found that the amount of strong acidity at 300 -5 50-C on Fe-modified samples was decreased,going with another new acid site appearance at 550- 600-C and that Fe/HZSM-5 catalysts were highly selective towards light olefins,especially the 9FZ sample.In addition,Fe-modified catalysts suppressed the conversion of ethanol to aromatics and paraffins and enhanced their anti-carbon deposit ability.
引用
收藏
页码：423 / 427
页数：5
相关论文
共 50 条
  • [11] Catalytic Conversion of Bio-ethanol to Ethylene over La-Modified HZSM-5 Catalysts in a Bioreactor
    Ouyang, Jia
    Kong, Fengxia
    Su, Guodong
    Hu, Yaochi
    Song, Qilei
    CATALYSIS LETTERS, 2009, 132 (1-2) : 64 - 74
  • [12] Catalytic cracking of n-heptane over Fe modified HZSM-5 nanosheet to produce light olefins
    Wang, Jie
    Shan, Junwei
    Tian, Yajie
    Zhu, Tiantian
    Duan, Haonan
    He, Xinyu
    Qiao, Congzhen
    Liu, Guozhu
    FUEL, 2021, 306
  • [13] Reaction network of the chloromethane conversion into light olefins using a HZSM-5 zeolite catalyst
    Gamero, Monica
    Valle, Beatriz
    Castano, Pedro
    Aguayo, Andres T.
    Bilbao, Javier
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2018, 61 : 427 - 436
  • [14] Nonoxidative methane activation, coupling, and conversion to ethane, ethylene, and hydrogen over Fe/HZSM-5, Mo/HZSM-5, and Fe-Mo/HZSM-5 catalysts in packed bed reactor
    Bajec, David
    Kostyniuk, Andrii
    Pohar, Andrej
    Likozar, Blaz
    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2019, 43 (13) : 6852 - 6868
  • [15] Performance of hierarchical HZSM-5 for the conversion of ethanol to hydrocarbon
    Ramasamy, Karthikeyan
    Zhang, He
    Sun, Junming
    Wang, Yong
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [16] Conversion of ethanol to hydrocarbons on hierarchical HZSM-5 zeolites
    Ramasamy, Karthikeyan K.
    Zhang, He
    Sun, Junming
    Wang, Yong
    CATALYSIS TODAY, 2014, 238 : 103 - 110
  • [17] CONVERSION OF ETHANOL TO AROMATICS ON HZSM-5 IN A PULSE MICROREACTOR
    CHOUDHARY, VR
    SANSARE, SD
    APPLIED CATALYSIS, 1984, 10 (02): : 147 - 153
  • [18] HZSM-5 catalysed conversion of aqueous ethanol to hydrocarbons
    Talukdar, AK
    Bhattacharyya, KG
    Sivasanker, S
    APPLIED CATALYSIS A-GENERAL, 1997, 148 (02) : 357 - 371
  • [19] The role of the compositions of HZSM-5 zeolites modified with nanosized anatase in propane and ethanol conversion
    Domoroshchina, Elena
    Kravchenko, Galina
    Kuz'micheva, Galina
    Markova, Ekaterina
    Zhukova, Anna
    Pirutko, Larisa
    Khramov, Evgeniy
    Dorokhov, Andrey
    Koroleva, Alexandra
    CATALYSIS TODAY, 2022, 397 : 511 - 525
  • [20] Research progress of gallium modified HZSM-5 catalysts for aromatization of light alkanes
    Wu Y.
    Zhang Y.
    Wu Q.
    Shi D.
    Chen K.
    Li H.
    Huagong Jinzhan/Chemical Industry and Engineering Progress, 2023, 42 (10): : 5162 - 5178
12345