Studies on extraction of In(Ⅲ) with 8-hydroxyquinoline

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中国国家自然科学基金;
关键词
Extraction; equilibrium constant; Pitzer’s equation;
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O658 [元素及化合物的分离方法];
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摘要
The equilibrium molalities of In3+ in extraction reaction: In3+(aq)+3HOx(org) = In(Ox)3(org) + 3H+(aq) were measured at ionic strengths from 0.13 to 2.54 mol-kg-1 in the aqueous phase containing Na2SO4 as the supporting electrolyte and at constant initial molality of extractant, HOx, in the organic phase at temperatures from 278.15 to 308.15 K, where HOx and Ox mean 8-hydroxy-quinoliue and its anion, respectively. The standard extraction constants K0 at various temperatures were obtained by two methods proposed in our previous paper.
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页码:19 / 25
页数:7
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