Studies on extraction of In(Ⅲ) with 8-hydroxyquinoline

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作者
SONG
机构
基金
中国国家自然科学基金;
关键词
Extraction; equilibrium constant; Pitzer’s equation;
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中图分类号
O658 [元素及化合物的分离方法];
学科分类号
摘要
The equilibrium molalities of In3+ in extraction reaction: In3+(aq)+3HOx(org) = In(Ox)3(org) + 3H+(aq) were measured at ionic strengths from 0.13 to 2.54 mol-kg-1 in the aqueous phase containing Na2SO4 as the supporting electrolyte and at constant initial molality of extractant, HOx, in the organic phase at temperatures from 278.15 to 308.15 K, where HOx and Ox mean 8-hydroxy-quinoliue and its anion, respectively. The standard extraction constants K0 at various temperatures were obtained by two methods proposed in our previous paper.
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页码:19 / 25
页数:7
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