A novel reductive ring-opening reaction of isoxazolidine to form functionalized 1,3-aminoalcohol

被引：0

作者：

Wing Hong Chan ^{[1
]}

Albert W.M. Lee ^{[1
]}

Wai Yeung Wong ^{[1
]}

机构：

[1] Department of Chemistry Hong Kong Baptist University Kowloog Tong Hong Kong

来源：

ChineseChemicalLetters | 2007年 / 06期

关键词：

Isoxazolidine; Hydrogenation; Raney nickel; 1,3-Amino-alcohol;

D O I：

暂无

中图分类号：

O621.25 [];

学科分类号：

摘要：

Reductive cleavage of the N-O bond of isoxazolidine ring with catalytic hydrogenation over Raney nickel was described. Bicyclic isoxazolidines could be effectively converted into the corresponding 1,3-amino-alcohol possessing a sultone or sultam moiety with high conversion and yield when the hydrogenation was catalyzed by freshly prepared Raney nickel under a pressure of 40 psi in the presence of triethylamine.

引用

页码：629 / 632

页数：4

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