Intramolecular O-Sn coordination in (Z)-1-(triphenylstannyl)-3-phenyl-1-buten-3-ol: Evidence by X-ray diffracation analysis and bromination

被引：0
|
作者：
FU
机构：
来源：
Chinese Journal of Chemistry | 1994年 / 04期
关键词：
Sythesis; X-ray diffraction analysis; (Z)-l-(triphenylstannyl)-3-phenyl-l-buten-3-ol;
D O I：
暂无
中图分类号：
O657.3 [光化学分析法（光谱分析法）];
学科分类号：
070302 ; 081704 ;
摘要：
The synthesis and properties of (Z)-1-(triphenylstannyl)-3-phenyl-1-buten-3-ol (1) are described. Compound 1 crystallizes from alcohol in the monoclinic space group P21/c with unit-cell dimensions a=9.296(2), 6=14.081(3), c=18.390(5) A,B=97.70(2), V=2385.5(1) A3, Z=4, F(000)=1008, Dc=1.38 g.cm-3,u=10.88 cm-1, final R=0.0359 for 3079 observed reflection [I > 3(I)]. The X-ray diffraction analysis of this compound shows the presence of an intramolecular coordination to the tin atom giving rise to a five-membered ring in which the metal exhibits a distroted trignoal bipyramidal geometry; as a consequence, a phenyl group, probably the apical one, is cleaved more easily by bromine than the vinyl substituent.
引用
收藏
页码：365 / 371
页数：7
相关论文
共 50 条
  • [21] 1-Pentyl-3-(4-methoxy-1-naphthoyl)indole and 2-(2-methoxy-phenyl)-1-(1-pentyl-1H-indol-3-yl)-ethanone: X-ray structures and computational studies
    Nycz, Jacek E.
    Malecki, Grzegorz
    Zawiazalec, Marcin
    Pazdziorek, Tadeusz
    Skop, Patrycja
    JOURNAL OF MOLECULAR STRUCTURE, 2010, 984 (1-3) : 125 - 130
  • [22] X-ray structure analysis of 1-(4-bromophenyl)-3-(4-chlorophenyl)-prop-2-en-1-one
    Yang, Wen
    Wang, Lei
    Zhang, Dechun
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2006, 36 (03) : 195 - 198
  • [23] X-ray structure analysis of 1-(4-bromophenyl)-3-(4-chlorophenyl)-prop-2-en-1-one
    Wen Yang
    Lei Wang
    Dechun Zhang
    Journal of Chemical Crystallography, 2006, 36 : 195 - 198
  • [24] Quantitative x-ray diffraction analysis of strain and interdiffusion in β-Ga2O3 superlattices of μ-Fe2O3 and β-(AlxGa1-x)2O3
    Hettiaratchy, Elline C.
    Wang, Binbin
    Dheenan, Ashok
    McGlone, Joe
    Kalarickal, Nidhin Kurian
    Bagues, Nuria
    Ringel, Steven
    McComb, David W.
    Rajan, Siddharth
    Myers, Roberto C.
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2022, 40 (06):
  • [25] X-RAY STRUCTURE-ANALYSIS OF 3-[3-BENZOYL-4-(DIETHYLAMINO)-5-METHYL-1-PYRAZOLYL]-3-(DIETHYLAMINO)-2-METHYL-1-PHENYL-2-PROPEN-1-ONE, THE 1 - 2 REACTION-PRODUCT OF DIBENZOYLDIAZOMETHANE AND 1-(DIETHYLAMINO)PROPYNE
    GIEREN, A
    LAMM, V
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (MAR): : 844 - 848
  • [26] Six-Membered Electron Transfer Series [V(dithiolene)3]Z (z=1+, 0, 1-, 2-, 3-, 4-). An X-ray Absorption Spectroscopic and Density Functional Theoretical Study
    Sproules, Stephen
    Weyhermueller, Thomas
    DeBeer, Serena
    Wieghardt, Karl
    INORGANIC CHEMISTRY, 2010, 49 (11) : 5241 - 5261
  • [27] Preparation, X-ray phase analysis and dielectric properties of Pb(Fe1-xCox)2/3W1/3O3 and Pb(Co1-yFey)1/2W1/2O3 (0 ≤ x, y ≤ 1) systems
    Fedulov, Dmitriy
    Kozlov, Vladislav
    Bush, Alexander
    Talanov, Mikhail
    CERAMICS INTERNATIONAL, 2022, 48 (22) : 33219 - 33228
  • [28] X-ray powder diffraction data for 5, 6-dihydro-3-(4-morpholinyl)-1-[4-(2-oxo-1-piperidinyl) phenyl]-2(1H)-pyridinone, C20H25N3O3
    Wang, Qing
    Zeng, Xia
    Li, Shan Shan
    Ma, Xiao Li
    Li, Hui
    POWDER DIFFRACTION, 2016, 31 (04) : 288 - 291
  • [29] X-ray structure analysis of lead magnesium niobate PbMg1/3Nb2/3O3 at low temperatures
    Chernyshev, VV
    Zhukov, SG
    CRYSTALLOGRAPHY REPORTS, 1998, 43 (02) : 171 - 174
  • [30] X-ray structure analysis of lead magnesium niobate PbMg1/3Nb2/3O3 at low temperatures
    Kristallografiya, 43 (02): : 206 - 209
12345