Thermal Behavior Study of Carbonate Inorganic Materials

被引：0
|
作者：
Zhiyue Han [1 ]
Yuezhen Yang [1 ]
Zhiming Du [1 ]
Qian Yao [1 ]
Chunying Wang [1 ]
机构：
[1] State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology
来源：
JournalofBeijingInstituteofTechnology | 2017年 / 26卷 / 01期
关键词：
carbonate; coolant; non-isothermal kinetic parameters; thermal decomposition mechanism;
D O I：
10.15918/j.jbit1004-0579.201726.0105
中图分类号：
TQ569 [灭火器与灭火用剂的生产];
学科分类号：
0817 ;
摘要：
The thermal decomposition processes of（MgCO;）;·Mg（OH）;·5H;O（MCH）,5ZnO·2CO;·4H;O（ZCH）,NiCO;·2Ni（OH）;·4H;O（NCH）,PbCO;（LC）and [Cr（OH）;];·CO;·8H;O（CC）were studied via TG-DSC.The results of research imply that MCH has the largest capacity of heat absorption and ZCH is second to MCH among the studied materials.The non-isothermal kinetic parameters of MCH and ZCH were calculated by Kissinger and Ozawa methods.Furthermore,thermal decomposition mechanisms of MCH and ZCH were investigated by Coats-Redfern method.Due to the large specific heat capacity,MCH and ZCH are promising to be used as a coolant in extinguishant formulations.
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页码：29 / 37
页数：9
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